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The chemistry of cationic polymerization /
The Chemistry of Cationic Polymerization.
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford :
Symposium Publications Division, Pergamon Press,
1963.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; The Chemistry of Cationic Polymerization; Copyright Page; Dedication; Foreword; Table of Contents; INTRODUCTION; CHAPTER 1. CARBONIUM IONS; 1. CLASSICAL CARBONIUM IONS; 2. THE EXPERIMENTAL EVIDENCE FOR CARBONIUM IONS; 3. THE STABILITY OF CARBONIUM IONS; 4. CARBONIUM IONS FROM OLEFINS; 5. NON-CLASSICAL CARBONIUM IONS; REFERENCES; CHAPTER 2. ORGANIC REACTIONS RELATED TO CATIONIC POLYMERIZATION; 1. INTRODUCTION; 2. THE FORMATION OF CARBONIUM IONS; 3. THE REACTIONS OF CARBONIUM IONS WITH ANIONSAND RELATED NUCLEOPHILIC REAGENTS; 4. THE ELIMINATION REACTIONS OF CARBONIUM IONS
- 5. THE REACTIONS OF CARBONIUM IONS WITH BONDED HYDROGEN ATOMS6. THE REARRANGEMENTS OF CARBONIUM IONS; 7. ADDITION OF CARBONIUM IONS TO OLEFINS ANDITS CONVERSE
- CATIONIC FRAGMENTATION REACTIONS; 8. THE REACTIONS OF CARBONIUM IONSWITH AROMATIC COMPOUNDS; 9. CONCLUSIONS; REFERENCES; CHAPTER 3. A COMPARISON OF THE RADICAL, CATIONIC AND ANIONIC MECHANISMS OF ADDITION POLYMERIZATION; 1. THE PRINCIPAL CHAIN MECHANISMS; 2. CATALYSTS, INITIATORS AND CHAIN INITIATION; 3. THE GROWTH REACTION; 4. COMPETITIVE PROCESSES; 6. DIAGNOSIS OF REACTION MECHANISM; REFERENCES; 7. APPENDIX; REFERENCES TO APPENDIX
- CHAPTER 4. ISOBUTENE1. INTRODUCTION; 2. THE PECULIARITY OF ISOBUTENE; 3. THE STRUCTURE OF POLYISOBUTENE; 4. CATALYTIC SYSTEMS; 5. KINETIC INVESTIGATIONS; REFERENCES; 6. APPENDIX; CHAPTER 5. ALIPHATIC MONO-OLEFINS OTHER THAN ISOBUTENE; 1. INTRODUCTION; 2. INDUSTRIAL APPLICATIONS; 3. GENERAL CONSIDERATIONS; 4. KINETIC STUDIES; 5. MISCELLANEOUS STUDIES; 6. MECHANISMS OF REACTION; REFERENCES; APPENDIX; CHAPTER 6. STYRENE; 1. INTRODUCTION; 2. THE FORMATION OF IONS FROM STYRENE; 3. CO-CATALYSIS; 4. THE OVERALL KINETICS, AND THE MJECHANISM0; F INITIATION AND PROPAGATION
- 5. CYCLIZATION A N D ISOMERIZATION OF UNSATURATEDPOLYMERS6. CONCLUSION; REFERENCES; CHAPTER 9. VINYL ETHERS; 1. INTRODUCTION; 2. THE CATIONIC MECHANISM; 3. THE KINETIC SCHEME; 4. EXPERIMENTAL METHODS; 5. LEWIS A C I D S AS CATALYSTS; 6. CATALYTIC ACTION OF IODINE; 7. THE SIDE CHAIN EFFECT; 8. THE INTERHALOGEN COMPOUNDS AS CATALYSTS; 9. BORON FLUORIDE AS CATALYST; 10. LOW TEMPERATURE POLYMERIZATION; 11. ZIEGLER CATALYSTS; 12. ISOTACTIC POLYMERS FROM HOMOGENEOUS SYSTEMS; REFERENCES; CHAPTER 10. EPOXIDES; 1. INTRODUCTION; 2. BORON FLUORIDE COMPLEXES