Advances in metal-organic chemistry. Volume 2 /

Advances in Metal-Organic Chemistry.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Liebeskind, Lanny S. (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: London : JAI Press, [1991]
Colección:Advances in Metal-Organic Chemistry.
Temas:
Organometallic chemistry.
Chimie organom�etallique.
SCIENCE > Chemistry > Organic.
Organometallic chemistry
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Advances in Metal-Organic Chemistry: A Research Annual; Copyright Page; Table of Contents; LIST OF CONTRIBUTORS; INTRODUCTION; CHAPTER 1. SYNTHETIC APPLICATIONS OF CHROMIUM TRICARBONYL STABILIZED BENZYLIC CARBANIONS; I. INTRODUCTION; II. PREPARATION OF ARENE CHROMIUM TRICARBONYL COMPLEXES; III. DECOMPLEXATION OF ARENE CHROMIUM TRICARBONYL COMPLEXES; IV. BENZYLIC CARBANIONS DERIVED FROM (C6H5R)CHROMIUM TRICARBONYL COMPLEXES; V. BENZYLIC CARBANIONS DERIVED FROM THE CHROMIUM TRICARBONYL COMPLEXES OF XYLENES, INDANES AND TETRALINS.
  • XII. CONCLUSIONSREFERENCES AND NOTES; CHAPTER 2. PALLADIUM-MEDIATED ARYLATION OF ENOL ETHERS; I. INTRODUCTION; II. BACKGROUND: HECK ARYLATION; III. PALLADIUM-MEDIATED ARYLATION OF ENOL ETHERS; IV. CONCLUSIONS; REFERENCES AND NOTES; CHAPTER 3. TRANSITION METAL CATALYZED SILYLMETALATION OF ACETYLENES AND ET3B-INDUCED RADICAL ADDITION OF PH3SNH TO ACETYLENES; I. INTRODUCTION; II. SILYLMETALATION OF ACETYLENES AND ITSAPPLICATION TO THE STEREOSELECTIVE SYNTHESIS OF STEROIDAL SIDE CHAINS; III. DEVELOPMENT OF PhMe2SiZnR2Li REAGENT AND ITSCHARACTERISTICS.
  • IV. DISILYLATION OF ACETYLENES WITH Si-Mn REAGENTSV. TRANSITION METAL CATALYZED ADDITION OF PhMe2SiBEt3Li TO ACETYLENES IN THE PRESENCE OF METHANOL; VI. Et3B INDUCED RADICAL ADDITION OF R3SnH AND R3GeH TO ACETYLENES; ACKNOWLEDGEMENTS; REFERENCES AND NOTES; CHAPTER 4. DEVELOPMENT O F CARBENE COMPLEXES OF IRON AS NEW REAGENTS FOR SYNTHETIC ORGANIC CHEMISTRY; I. INTRODUCTION; II. OUR EARLY STUDIES: DEVELOPMENT OF A METHYLENE TRANSFER REAGENT; III. An Ethylidene Transfer Reagent; IV. AN ALTERNATIVE APPROACH TO ALKYLIDENE COMPLEXES: PROTONATION OF ALKENYL COMPLEXES.

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