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Organosilicon chemistry, 2 : plenary lectures presented at the second International Symposium on Organosilicon Chemistry held in Bordeaux, France, 9-12 July 1968 /
Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhaloge...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores Corporativos: | , , |
| Formato: | Electrónico Congresos, conferencias eBook |
| Idioma: | Inglés Francés Alemán |
| Publicado: |
London :
Butterworths,
[1969]
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Organosilicon Chemistry 2; Copyright Page; Table of Contents; CHAPTER 1. ANIONIC REARRANGEMENTS OF ORGANOSILICON COMPOUNDS; Types of anionic rearrangements; The silylhydrazine rearrangement: origins; The catalytic silylhydrazine rearrangement; Mechanism and rate; Unique mobility of silicon in anionic rearrangement; The Anti-Wittig rearrangement of silicon; Unknown 1,2 anionic rearrangements; Remote anionic rearrangements; Summary; References; CHAPTER 2. ON POLYMERIZATION OF ORGANOSILICON CYCLIC COMPOUNDS; POLYMERIZATION OF ORGANOCYCLOSILOXANES.
- POLYMERIZATION OF POLYCYCLIC COMPOUNDS, ORGANOCYCLOSILSESQUIOXANESPOLYMERIZATION OF ORGANOCYCLOSILAZANES; References; CHAPTER 3. N-METALLATED SILICON-NITROGEN DERIVATIVES: PREPARATION, STRUCTURE AND REACTIONS; CHAPTER 4. DIVALENT SILICON INTERMEDIATES IN THE PYROLYSIS OF ALKOXYPOLYSILANES; References; CHAPTER 5. ORGANOSILICON AND ORGANOGERMANIUM DERIVATIVES WITH SILICON-METAL AND GERMANIUM-METAL BONDS; References; CHAPTER 6. SOME RECENT STUDIES OF THE CLEAVAGE OF CARBON-SILICON AND RELATED BONDS; NUCLEOPHILIC CLEAVAGE OF BENZYL-SILICON AND RELATED BONDS.
- CLEAVAGE OF ARYL-SILICON AND RELATED BONDSCLEAVAGE OF ALKYNYL-SILICON AND RELATED BONDS; CONCLUSION; References; CHAPTER 7. THE CHEMISTRY OF TRICHLOROSILANE IN THE PRESENCE OF TERTIARY AMINES; PHENYLACETYLENE; p-METHOXYPHENYLACETYLENE AND m-TRIFLUOROMETHYLPHENYLACETYLENE; OTHER ACETYLENES; MECHANISM; DEUTERIUM EXCHANGE EXPERIMENTS; References; CHAPTER 8. COMPOSES DU SILICIUM BIOLOGIQUEMENT ACTIFS; Bibliographie; CHAPTER 9. INTRA-UND INTERMOLEKULARE WECHSELWIRKUNGEN IN EINIGEN ORGANOSILICIUMVERBINDUNGEN; EINLEITUNG; SUBSTITUENTENEINFLU� AUF DIE OH-BINDUNG IN TRIORGANOSILANOLEN.
- SUBSTITUENTENEINFLU� AUF DIE BINDUNGEN IN IN METHYLMETHOXY-UND METHYLCHLORSILANENBINDUNGSBEEINFLUSSUNGEN �UBER DIE SILOXANKETTE; EINIGE MASSENSPEKTROMETRISCHE AUSSAGEN �UBER SUBSTITUENTENEINFL�USSE; ZUR ASSOZIATION EINIGER TRIORGANOFLUORSILANE; Literatur; CHAPTER 10. PROPERTIES OF SILICON DERIVATIVES OF COBALT, MANGANESE AND IRON CARBONYLS; I. SYNTHESIS; II. THERMOCHEMICAL DATA; III. STRUCTURE; IV. BONDING; V. THERMAL STABILITY; VI. OXIDATIVE STABILITY (TO OXYGEN); VII. CLEAVAGE OF THE SILICON-TRANSITION METAL BOND; VIII. SUBSTITUTION REACTIONS AT SILICON.
- IX. SUBSTITUTION REACTIONS AT THE TRANSITION METALX. CONCLUSIONS; References; CHAPTER 11. SILYLATIONS OF SOME POLYHALOGENATED COMPOUNDS; INTRODUCTION; POLYSILYLATIONS OF SOME HIGHLY HALOGENATED AROMATIC COMPOUNDS; POLYSILYLATIONS OF SOME HIGHLY HALOGENATED ALIPHATIC COMPOUNDS; POLYSILYLATIONS OF SOME HIGHLY HALOGENATED HETEROCYCLIC AND MISCELLANEOUS COMPOUNDS; PROPERTIES AND SOME CHEMICAL REACTIONS OF TETRAKIS (TRIMETHYLSILYL) ALLENE (I); PROPERTIES AND SOME CHEMICAL REACTIONS OF HEXAKIS (TRIMETHYLSILYL) BUT-2-YNE (XXI); SUMMARY; References.