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Coordination chemistry-- XIV : plenary lectures presented at the 14th International Conference on Coordination Chemistry held at Toronto, Canada 22-28 June 1972 /

Coordination Chemistry-XIV provides information pertinent to the fundamental characteristics and synthesis of coordination compounds. This book discusses the importance of undertaking accurate X-ray analysis of a wide-ranging series of complexes in order to derive more secure theoretical correlation...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores Corporativos: International Conference on Coordination Chemistry Toronto, Ont., International Union of Pure and Applied Chemistry, National Research Council Canada, Chemical Institute of Canada
Otros Autores: Lever, A. B. P. (Alfred Beverley Philip) (Editor )
Formato: Electrónico Congresos, conferencias eBook
Idioma:Inglés
Publicado: London : Butterworths, [1973]
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Coordination Chemistry-XIV; Copyright Page; Table of Contents; ORGANIZING COMMITTEE; CHAPTER 1. SYNTHESIS AND PROPERTIES OF TRANSITION METAL TO CARBON BONDS; ABSTRACT; INTRODUCTION; TITANIUM AND ZIRCONIUM; METAL-CARBON BONDS IN MACROCYCLIC COMPLEXES WITH DELOCALIZED UNSATURATION; ORGANOMETALLIC DERIVATIVES OF GROUP VII TRANSITION ELEMENTS; METAL CARBONYLS AS A SOURCE OF ZEROVALENT METALS; STABLE URANIUM-ALKYL AND URANIUM-ARYL BONDS; ACKNOWLEDGMENT; REFERENCES; CHAPTER 2. NEW ROUTES TO, AND REACTIONS OF POLYHEDRAL TRANSITION METAL CARBORANE SPECIES; ABSTRACT.
  • THE POLYHEDRAL EXPANSION METHODREDUCTION AND POLYHEDRAL EXPANSION OF THE ICOSAHEDRAL 1,2-B10C2H12 CARBORANE; THE POLYHEDRAL CONTRACTION METHOD; REFERENCES; CHAPTER 3. ORGANO-TRANSITION METAL CHEMISTRY WITHOUT PHOSPHINES: THE PALLADIUM CATALYSED CYCLOTRIMERIZATION OF ACETYLENES; ABSTRACT; REACTIONS WITH PALLADIUM (0); REACTIONS WITH PALLADIUM (ii); A 'LIGHTLY STABILIZED' PALLADIUM (II) MODEL COMPLEX; REFERENCES; CHAPTER 4. STRUCTURAL INORGANIC CHEMISTRY AND DIFFRACTION METHODS: METAL-LIGAND BONDS IN POLYNUCLEAR COMPLEXES AND ON METAL SURFACES; ABSTRACT; INTRODUCTION.
  • Electron-deficient and electron-precise bridged binuclear complexesbridged complexes of transition metals; some prospects; cluster complexes in redox proteins; organometallic chemistry of transition metal surfaces; references; chapter 5. octahedral substitution mechanisms and reactive intermediates; abstract; scope and purpose; aquation and anation or substitution; properties of the intermediates; base hydrolysis; synthesis; nucleophilic reactions; electrophilic substitution; acknowledgment; references.
  • CHAPTER 6. RECENT ADVANCES IN THE CHEMISTRY OF VITAMIN B12 AND VITAMIN B12 MODEL COMPOUNDS: REDUCTIVE COBALT-CARBON BOND CLEAVAGE REACTIONSABSTRACT; INTRODUCTION; THE REDUCTIVE COBALT-CARBON BOND CLEAVAGE BY THIOLS AND DITHIOLS; METHYL GROUP TRANSFER REACTIONS; REDUCTIVE Co-C BOND CLEAVAGE BY ALKALINE CARBON MONOXIDE AND OTHER REDUCING AGENTS; COMPARISON WITH ENZYMATIC REACTIONS; ACKNOWLEDGEMENTS; REFERENCES; CHAPTER 7. REACTIONS OF CARBON DIOXIDE WITH TRANSITION METAL COMPOUNDS; ABSTRACT; REFERENCES; CHAPTER 8. SUBSTITUTION PROCESSES IN SIMPLE AND COMPLICATED METAL COMPLEXES; ABSTRACT.
  • REPLACEMENT OF UNIDENTATE LIGANDSEFFECT OF PROTONATION OF THE ENTERING LIGAND; COMPLEXING WITH MULTIDENTATE LIGANDS; METALLOENZYMES; ACKNOWLEDGEMENT; REFERENCES; CHAPTER 9. INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY; CHAPTER 10. INTERNATIONAL UNION OF PURE AND APPLIED CHEMISTRY; CHAPTER 11. TABLES OF WAVENUMBERS FOR THE CALIBRATION OF INFRARED SPECTROMETERS IN THE RANGE 600-1 cm-1; INTRODUCTION; PART III: TABLES FOR THE CALIBRATION OF MODERATELY HIGH RESOLUTION SPECTROMETERS IN THE RANGE 600-1 cm-1.