Ions and ion pairs and their role in chemical reactions : invited lectures presented at the Symposium on Ions and Ion Pairs and their Role in Chemical Reactions, Syracuse, NY, USA, 30 May-2 June 1978 /

Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state....

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores Corporativos: Symposium on Ions and Ion Pairs and their Role in Chemical Reactions Syracuse, N.Y., International Union of Pure and Applied Chemistry. Physical Chemistry Division, College of Environmental Science and Forestry, National Science Foundation (U.S.)
Otros Autores: Smid, Johannes (Editor )
Formato: Electrónico Congresos, conferencias eBook
Idioma:Inglés
Publicado: Oxford : Pergamon Press, [1979]
Temas:
Ions > Congresses.
Chemical reaction, Conditions and laws of > Congresses.
Ions > Congr�es.
R�eactions chimiques > M�ecanismes > Congr�es.
SCIENCE > Chemistry > Physical & Theoretical.
Chemical reaction, Conditions and laws of.
Ions.
Congress
Conference papers and proceedings.
Actes de congr�es.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Ions and Ion Pairs and their Role in Chemical Reactions; Dedication; Copyright Page; Table of Contents; PREFACE; CHAPTER 1. STRUCTURE OF SOLVATED ION PAIRS FROM ELECTRIC DIPOLE MOMENTS; Abstract; INTRODUCTION; EXPERIMENTAL VARIABLES; CALCULATION OF DIPOLE MOMENTS; EXPERIMENTAL RESULTS; NATURE OF SOLVATION COMPLEXES; Acknowledgement; REFERENCES; CHAPTER 2. INFORMATION ON ION-SOLVENT INTERACTIONS OBTAINED FROM THE STUDY OF ISOLATED COMPLEXES CONTAINING THE ION AND A SMALL NUMBER OF SOLVENT MOLECULES; Abstract; INTRODUCTION; ION SOLVENT MOLECULE EQUILIBRIA; REFERENCES.
  • CHAPTER 3. STRUCTURE OF ALKALI BIPHENYL ION PAIRS IN SOLUTION AND IN THE SOLID STATEAbstract; INTRODUCTION; EXPERIMENTAL; NMR EXPERIMENTS ON SOLUTIONS; CRYSTAL STRUCTURES OF NaBp. 2Tg, KBp. 2Ttg AND RbBp. 2Ttg; MAGNETIC EXPERIMENTS ON SOLIDS; Acknowledgement; REFERENCES; CHAPTER 4. OPTICAL AND NMR INVESTIGATIONS ON ALKALI ION PAIRS OF CARBANIONS AND NITRANIONS; Abstract; INTRODUCTION; ALKALI ION PAIRS OF CARBANIONS AND NITRANIONS; DISCUSSION OF THE ABSORPTION AND FLUORESCENCE ION PAIR SHIFTS; NMR EVIDENCE FOR THE ION PAIR STRUCTURES; PROTON EXCHANGE REACTION BETWEEN INDENE AND INDENYL.
  • CONCLUDING REMARKSAcknowledgement; REFERENCES; CHAPTER 5. MULTINUCLEAR NMR STUDIES OF ALKALI IONS IN NONAQUEOUS SOLVENTS; INTRODUCTION; CONCENTRATION DEPENDENCE OF CHEMICAL SHIFTS; INFLUENCE OF SOLVENTS; COMPLEXATION REACTIONS; ""BASEBALL"" COMPLEX; CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; CHAPTER 6. MACROCYCLIC LIGANDS ON POLYMERS; Abstract; INTRODUCTION; SYNTHESIS AND CATION BINDING PROPERTIES OF POLY (CROWN ETHERS); BINDING OF ORGANIC SOLUTES TO POLY (CROWN ETHERS); CATALYSIS WITH POLY (CROWN ETHERS); POLY (CROWN ETHER) COMPLEXES WITH MACROMOLECULES; Acknowledgment; REFERENCES.
  • CHAPTER 10. THE REACTION OF CATIONS WITH ANIONS IN SOLUTIONAbstract; INTRODUCTION; GENERAL CONCEPTS; COMPUTATIONAL RESULTS; CONCLUSIONS; ACKNOWLEDGEMENTS; REFERENCES; CHAPTER 11. FORMATION AND REACTIVITIES OF FREE IONS IN CATIONIC POLYMERISATION; Abstract; INTRODUCTION; INITIATION VIA CARBOCATION SALTS; CATIONIC POLYMERISATION OF N-ETHYL-3-VINYLCARBAZOLE; STEREOREGULATION IN THE POLYMERISATION OF ALKYL VINYL ETHERS; PROMOTION OF CATIONIC POLYMERISATION WITH FREE RADICAL INITIATORS; TRIBUTE TO MICHAEL SZWARC; REFERENCES.

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