Periodate oxidation of diol and other functional groups : analytical and structural applications /
Periodate Oxidation of Diol and Other Functional Groups: Analytical and Structural Applications deals with the chemistry of organic periodate oxidations with special reference to the study of carbohydrates, along with their analytical and structural applications. This book explores the mechanistic a...
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Oxford :
Pergamon Press,
[1970]
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Edición: | First edition. |
Colección: | Monographs in organic functional group analysis ;
volume 2. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Periodate Oxidation of Diol and Other Functional Groups: Analytical and Structural Applications; Copyright Page; Table of Contents; PREFACE; INTRODUCTION; CHAPTER 1. HISTORY; Literature Cited; CHAPTER 2. PREPARATION AND PROPERTIES OF PERIODATES; Preparation; Solubility; Stability of Aqueous Solutions; Standard Potentials; Ionization of Periodic Acid; Structure of Periodates; Literature Cited; CHAPTER 3. MECHANISM OF PERIOD ATE OXIDATION; 1,2-Diols; 1,2-Hydroxycarbonyl Compounds and 1,2-Diketones; 1,2-Aminoalcohols; Active M�ethyl�ene Groups; Literature Cited.
- CHAPTER 4. ANOMALOUS PERIODATE OXIDATIONSOveroxidation; Sulfur-containing Compounds; Phenols; Flavanols; Amines; Amino Acids; Unsaturated Sugars; Amino Sugars; Proteins; Oxidations at Elevated Temperature; Oxidations in the Presence of Light; Literature Cited; CHAPTER 5. PERIODATE OXIDATION IN STRUCTURAL STUDIES; Structure Assignment based on Periodate Oxidation Information; Structure Assignment based on Periodate Oxidation and Other Information; Structure and End-group Assay of Polysaccharides; Nature of the Product of Periodate Oxidation; Literature Cited; CHAPTER 6. ANALYTICAL METHODS.
- Conditions of the OxidationDetermination of Oxidant Consumption; Other Methods for Periodate Determination; Determination of Acid Produced; Determination of Other Acids; Determination of Formaldehyde; Determination of Acetaldehyde; Determination of Ammonia and Amines; Determination of Carbon Dioxide; Recommended General Methods; Conclusions; Literature Cited; CHAPTER 7. SYNTHETIC AND OTHER APPLICATIONS OF PERIODATE OXIDATIONS; Literature Cited; AUTHOR INDEX; SUBJECT INDEX.