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Strained organic molecules /
Strained Organic Molecule, Volume 38 considers the vast field of strained organic molecules. The book discusses energy and entropy; cyclopropane and cyclobutane; and unique strained groupings or building blocks. The text also describes the aesthetics, rearrangements, and topology of polycycles; kine...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Academic Press,
1978.
|
| Colección: | Organic chemistry (New York, N.Y.) ;
v. 38. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- FrontCover; Strained Organic Molecules; Copyright Page; Table of Contents; Preface; CHAPTER 1. Energy and Entropy; 1. AReference States and Reference Books; 1. BOrigin of Molecular Strain; 1. CThermodynamics and Symmetry; 1. DPotential Energy Curves and Zero-Point Energy; CHAPTER 2. Cyclopropane and Cyclobutane; 2.A Conceptual Models for the Bonding in Cyclopropane; 2.B Selected Reactions of Cyclopropanes; 2.C Cyclobutane; CHAPTER 3. Unique Strained Groupings or Building Blocks; 3.A Cycloalkanes; 3.B Bicyclic, Spirocyclic, and Bridged Hydrocarbons; 3.C Tetrahedrane.
- 5.B Orbital Symmetry and Stabilities of Benzene Valence Isomers5.C Transition Metals and Strained Carbocyclic Molecules; 5.D Strained Heterocyclic Molecules; 5.E Substituted Derivatives of Strained Molecules; CHAPTER 6. A Potpourri of Pathologies; 6.A When is Tetracoordinate Carbon Tetrahedral?; 6.B Inverted Tetrahedra, Propellanes, Buttaflanes, and Paddlanes; 6.C Planar Methane and Its Derivatives; 6.D Five- and Six-Coordinate Carbon; Addendum; Index; ORGANIC CHEMISTRY.