Cargando…
The chemistry of pyrroles /
The Chemistry of Pyrroles, Volume 34 aims to provide a comprehensive survey of the synthesis of simple pyrroles and to present, wherever possible, a mechanistic and theoretical rationale for the multitude of reactions known for pyrroles. The book discusses the structure and reactivity of pyrrole; th...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London ; New York :
Academic Press,
1977.
|
| Colección: | Organic chemistry (New York, N.Y.) ;
v. 34. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; The Chemistry of Pyrroles; Copyright Page; Foreword; Abbreviations and Nomenclature; Table of Contents; Chapter 1. INTRODUCTION; References; Chapter 2. THE STRUCTURE AND REACTIVITY OF PYRROLE; A. Molecular and Electronic Structure of Pyrrole; B. Aromaticity and Resonance Energy; C. Molecular Orbital Calculations on Pyrroles; D. Theoretical Treatment of the Reactivity of Pyrrole with Electrophiles; References; Chapter 3. THE SYNTHESIS OF THE PYRROLE RING; A. Introduction; B. 2+2 Carbon Units; C. 1+3 Carbon Units; D. From Four Carbon Units; E. Ring-contractions.
- F. Miscellaneous ReactionsReferences; Chapter 4. ELECTROPHILIC SUBSTITUTION OF THE PYRROLE RING; A. Introduction; B. Protonation of the Pyrrole Ring; C. Nitration and Nitrosation; D. Halogenation; E. C-Alkylation Reactions; F. C-Acylation Reactions; G. Reactions with Carbonyl Compounds; H. Reactions of the Pyrryl Anion; I. Miscellaneous Electrophilic Reactions; J. Summary of the Reactivity of Pyrrole and Orientation Effects of Substituents; References; Chapter 5. OXIDATION AND REDUCTION OF THE PYRROLE RING; A. The Reactions of Pyrroles with Molecular Oxygen; B. Oxidation by Chemical Reagents.
- C. Anodic Oxidation of PyrrolesD. Reduction of the Pyrrole Ring; References; Chapter 6. REARRANGEMENT AND ADDITION REACTIONS; A. Thermal Rearrangements retaining the Pyrrole Ring; B. Photochemical Rearrangements retaining the Pyrrole Ring; C. Addition Reactions; D. Reactions with Radicals; References; Chapter 7. KETONES, ALDEHYDES AND CARBOXYLIC ACID DERIVATIVES OF PYRROLE; A. Resonance Interaction between the Pyrrole Ring and the Carbonyl Substituent; B. Chemical Reactivity; References; Chapter 8. ALKYLPYRROLES AND RELATED COMPOUNDS; B. Chemical Reactivity; C. Silylpyrroles.
- D. Pyrrolophanes and other Bridged PyrrolesReferences; A. Tautomerism; Chapter 9. HYDROXY- AND AMINOPYRROLES AND RELATED COMPOUNDS; A. Tautomerism; B. Synthesis; C. Chemical Reactivity; D. Pyrrylthiols; References; Chapter 10. AZAFULVENES; A. Structure and Reactivity; B. Synthesis; C. Spectroscopic Properties; References; Chapter 11. PHYSICO-ORGANIC PROPERTIES OF PYRROLE; A. Molecular Association; B. Basicity and Acidity Measurements; C. Dipole Moments; D. Polarographic Properties; E. Electronic Spectra; F. IR and Raman Spectra; G. NMR Spectra; H. Mass Spectra; References; Index.