Cargando…
Inorganic polymeric glasses /
The author describes a novel method of preparing hydrolysis-stable non-silicate glasses which is based on experimental work accomplished over the past twenty years. As such, the method is the beginning of a new approach to glass-making by the use of a molecularly-polymerizable precursor. The book el...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; New York :
Elsevier,
1992.
|
| Colección: | Studies in inorganic chemistry ;
15. |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover; Inorganic Polymeric Glasses; Copyright Page; Preface; Table of Contents; Introduction; Chapter 1. Introduction to Silicate Glass Technology; 1.1. Glass and Antiquity; 1.2. The Glassy or Vitreous State; 1.3. Glass Formers and Glass Compositions; 1.4. The Manufacture of Silicate-Based Glasses; 1.5. Forming and Finishing Operations; 1.6. Thermal Processing and Properties of Silicate Glasses; 1.7 Inherent Properties of Glass; 1.8 Silicate Glass Products Currently being Manufactured; Chapter 2. Introduction to Polymeric Glasses; 2.1. Prior Attempts to Prepare Stable Phosphate Glasses.
- 2.2. Structural Units in Glass2.3. Basis for Chain Structure of Polymerized Phosphates; 2.4. Prior Attempts to Prepare Phosphate Glasses by the Melting of Stoichiometric Compounds; 2.5. Crystalline Salt Monomers for Stable Phosphate Glass Preparation; Chapter 3. Factors Contributing to the Preparation of Stable Phosphate Glasses; 3.1. Anomalous Recrystallization of Polymeric Calcium Phosphate Glass; 3.2. Abnormal Strain Relief Behavior of Polymeric [Ca(PO3)2]n Glass; 3.3. The Effect of Melt-Hold-Time on Glass Points; 3.4. Measurement of Hydrolysis Stability of Polymerized Glasses.
- 3.5. Effects of Purity and Melt Hold Time on Hydrolysis Stability of Polymerized Glasses3.6. Effect of Melt Hold Time on Melt Viscosity; 3.7. Effect of Excess H3PO4 on the Reaction Paths of Monobasic Salts; 3.8. Effect of Ca/P Ratios on Stability of Polymerized Glass Compositions; 3.9. Other Polymerized Alkaline Earth Phosphate Glasses; 3.10. Effect of Crucibles Used to Hold the Melt during Polymerization; 3.11. The Combined Effects of Purity and MHT upon Polymerization; Chapter 4. Further Aspects of Polymerized Phosphate Glasses; 4.1. The Impurity Phase-Segregation Phenomenon.
- 4.2. Phase Separation as a Function of ""M"" in [CaM(PO3)2]n Glass4.3. Physical Properties of Fully Polymerized Phosphate Glasses; 4.4. Elimination of Striae and Other Optical Defects; 4.5. Spectral Properties and Ultraviolet Transparency; 4.6. Internal Diffusion Mechanisms and Modes of Chemical Attack; 4.7. Optimal Methods of Purification; 4.8. Other Inorganic Polymeric Glasses; Chapter 5. Uses of Polymeric Phosphate Glasses; 5.1. Nuclear Waste Sources; 5.2. History of Glass as a Nuclear Waste Encapsulent; 5.3. Polymeric Phosphate Glass and Nuclear Waste Encapsulation.
- 5.4. Properties of a Polymeric Phosphate Glass Containing Nuclear Waste5.5. Luminescent Polymeric Phosphate Glass and its Applications; 5.6 Other Potential Uses of Polymeric Glass; Subject Index.