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Tin in organic synthesis /
Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future develo...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London ; Boston :
Butterworths,
1987.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Tin in Organic Synthesis; Copyright Page; Foreword; Preface; Table of Contents; Abbreviations; Part One: Introduction to organotin chemistry; Chapter 1. General organotin chemistry; 1.1 Nomenclature; 1.2 Literature; 1.3 Tin and its bonds; 1.4 Some physical data; 1.5 Toxicity and hazards; Chapter 2. Preparation of organotin reagents; 2.1 Synthesis of basic organotin reagents; 2.2 Creation of a fresh tin-carbon bond; 2.3 Functional transformations of groups bound to tin; References; Part Two: Synthetic Applications Involving Tin-Hydrogen Bonds
- Chapter 3. Reduction of organic halides3.1 General; 3.2 Reduction of simple organic halides and polyhalides; 3.3 Chemoselective reduction of polyfunctional halides; 3.4 Stereochemistry; 3.5 Reductions with free-radical rearrangements or fragmentations; Chapter 4. Reduction of carbonyl compounds; 4.1 Aldehydes and ketones; 4.2 Acyl halides; 4.3 Esters and related compounds; Chapter 5. Reduction of thio, seleno and telluro compounds; 5.1 Thio derivatives; 5.2 Seleno derivatives; 5.3 Telluro derivatives; Chapter 6. Reduction of nitrogen compounds
- Part Four: Synthetic applications involving tin-heteroatom bondsChapter 11. Organotin alkoxides; 11.1 In substitution reactions; 11.2 In oxidation reactions; 11.3 In addition reactions; 11.4 As catalysts; Chapter 12. Organotin enolates; 12.1 Organotin(IV) enolates; 12.2 Tin(II) enolates; Chapter 13. Organotin oxides and peroxides; 13.1 Oxides; 13.2 Peroxides; Chapter 14. Organotin esters; 14.1 Carboxylates; 14.2 Other esters; Chapter 15. Organotin compounds with tin-nitrogen bonds; 15.1 Simple amines; 15.2 Other compounds with Sn-N bonds; Chapter 16. Organotin compounds with tin-sulphur bonds