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Analysis of organoaluminium and organozinc compounds /
Analysis of Organoaluminum and Organozinc Compounds, Volume 31 presents information pertinent to the organo compound of aluminum and zinc. This book discusses the growing interest in organoaluminum compounds as intermediates in the manufacture of organic chemicals. Comprised of nine chapters, this v...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford ; New York :
Pergamon Press,
[1968]
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| Edición: | First edition]. |
| Colección: | International series of monographs in analytical chemistry ;
volume 31. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Analysis of Organoaluminium and Organozinc Compounds; Copyright Page; Table of Contents; PREFACE; ACKNOWLEDGEMENTS; CHAPTER 1. ANALYSIS OF ORGANOALUMTNIUM COMPOUNDS CONTAINING ALKYL AND ALKOXTDE GROUPS UP TO BUTYL AND HYDRIDE GROUPS; 1.1 The two-stage sample decomposition-gas-liquid chromatographic method for determination of alkyl groups up to butyl and hydride groups; 1.2 The Dijkstra and Dahmen single stage decomposition-gas-liquid chromatographic method for determination of alkyl groups up to butyl and hydride groups.
- 1.3 Rapid plant control method for gas-liquid chromatographic analysis of dilute isopentane solutions of ethylaluminium compounds1.4 The Stauffer Chemical Company hydrolysis-gas chromatographic method for analysis of organoaluminium compounds; 1.5 Neumann N-methylaniline gasometric method for estimation of aluminium bound hydride groups; 1.6 Method for determination of aluminium-bound alkoxide groups up to butoxide; 1.7 The Bondarevskaya oxidation procedure for determining ethoxide groups in organoaluminium compounds.
- Method 1-Determination of alkyl groups up to butyl and hydride groups in organoaluminium and organozinc compounds. Alcoholysis-hydrolysis methodMethod 2-Determination of alkyl groups up to butyl and hydride groups in higher molecular weight organoaluminium compounds. Alcoholysishydrolysis method; Method 3-Determination of alkyl groups up to butyl and hydride groups in organoaluminium compounds. Laurie acid decomposition-GLC method; Method 4-Determination of ethyl, isobutyl, hydride, ethoxide and isobutoxide groups in isopentane solutions of triethylaluminium. Gas chromatographic method.
- Method 5-Determination of alkyl groups up to butyl and hydride groups in organoaluminium compounds. The Stauffer hydrolysis-gas chromatographic methodMethod 6-Determination of hydride content of organoaluminium compounds. Rapid N-methylaniline method; Method 7-Determination of alkoxide groups up to butoxide in reactive organoaluminium compounds; Method 8-Determination of alkoxide groups up to butoxide in less reactive types of organoaluminium compounds.
- CHAPTER 2. ANALYSIS OF HIGHER MOLECULAR WEIGHT ORGANOALUMINIUM COMPOUNDS CONTAINING ALKYL AND/OR ALKOXIDE GROUPS UP TO C2o-C30 AND HYDRIDE GROUPS2.1 Decomposition-gas-liquid chromatographic method for determination of aluminium-bound alkyl groups between C5 and C10; 2.2 Gas chromatographic methods for the determination of higher alkyl and/or alkoxide groups; 2.3 The acetylation method for determination of total alkoxide groups; 2.4 Separation of 'total alcohols' and 'total hydrocarbons' from hydrolysis product of higher molecular weight organoaluminium compounds.