Cargando…
Prediction of transport and other physical properties of fluids /
Prediction of Transport and Other Physical Properties of Fluids reviews general methods for predicting the transport and other physical properties of fluids such as gases and liquids. Topics covered range from the theory of corresponding states and methods for estimating the surface tension of liqui...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés Polaco |
| Publicado: |
Oxford ; New York :
Pergamon Press,
[1971]
|
| Edición: | First edition]. |
| Colección: | International series of monographs on chemical engineering ;
11. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Prediction of Transport and Other Physical Properties of Fluids; Copyright Page; Table Of contents; Notation; CHAPTER 1. GENERAL METHODS FOR ESTIMATING PHYSICO-CHEMICAL PROPERTIES OF GASES AND LIQUIDS; 1. INTRODUCTION; 2. BASIC INFORMATION ON GASES AND LIQUIDS; a. States of Matter; b. Properties of Molecules; c. Shape and Size of Molecules; d. Dipole Moments; e. Polarizability of Molecules; 3. INTERMOLECULAR FORCES; a. Energy of a System of Two Molecules; b. Calculation of the Intermolecular Force Constants.
- C. Application of the Lennard-Jones and Stockmayer Equations to the Estimation of some Physico-chemical Properties of Fluids4. CONSTITUTIVE AND ADDITIVE PROPERTIES OF CHEMICAL COMPOUNDS; a. Molal Volume; b. Molar Refraction; c. Parachor; d. Rheochor; e. Orthochor; f. Molar Velocity of Sound24; 5. METHODS FOR ESTIMATING THE CRITICAL CONSTANTS AS CONSTITUTIVE QUANTITIES; a. Relationship between the Structure and the Molecular Properties of a Compound and the Values of its Critical Parameters; b. Constants a and b in van der Waals' Equation.
- C. Calculation of the Critical Parameters from the Molar Refraction and the Parachord. Additive Estimation of the Critical Pressure; e. Additive Estimation of the Molal Critical Volume, V c; f. Additive Estimation of the Critical Temperature, T c; g. Additive Estimation of the Critical Parameters from Experimentally Determined Quan-tities such as Liquid Density, Boiling Temperature, etc; 6. GENERAL METHOD FOR CALCULATING ADDITIVE QUANTITIES; 7. SIMILARITY OF THE PHYSICO-CHEMICAL PROPERTIES OF SUBSTANCES; a. Conditions of Similarity.
- B. Application of the Principles of Similarity to the Determination of the Physico-chemical Properties of Substancesc. Physico-chemical Similarity of Compounds. Graphical Presentation of Relationships in the Form of a Straight Line; d. Comparison of Different Physico-chemical Properties of Different Compounds; 8. THEORY OF CORRESPONDING STATES; a. Scale Constants and Invariants; b. Corresponding States; c. Theory of Corresponding States. Theoretical Foundation; d. The ""Third Parameter"" in the Modified Theory of Corresponding States.
- E. Choice of the Best Method for Estimating the Critical ConstantsCHAPTER 2. SURFACE TENSION OF LIQUIDS; 1. BASIC RELATIONSHIPS; 2. DEPENDENCE OF SURFACE TENSION ON MOLECULAR PROPERTIES; 3. METHODS OF ESTIMATING THE SURFACE TENSION OF LIQUIDS; a. Estimation of the Surface Tension of a Liquid from the Parachor; b. Surface Tensions of Liquid Mixtures; d. Variation of Surface Tension with Temperature and Pressure; c. Prediction of Surface Tensions Using the Theory of Similarity; 4. RELATIONSHIP BETWEEN THE SURFACE TENSION AND VARIOUS OTHER PHYSICAL CONSTANTS; CHAPTER 3. VISCOSITIES OF GASES.