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140214r20111999enka ob 001 0 eng d |
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|a 017568031
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|a 871225412
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|a 9781782420569
|q (electronic bk.)
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|a 1782420568
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|z 9781898563501
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|a (OCoLC)874158519
|z (OCoLC)871225412
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|a QD561
|b .B874 2011eb
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|a MUS
|x 041000
|2 bisacsh
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|a 781.63
|2 23
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|a Burgess, John.
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|a Ions in solution :
|b basic principles of chemical interactions /
|c John Burgess.
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|a Second edition.
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|a Cambridge, England ;
|a Philadelphia, Pennsylvania ;
|a New Delhi, India :
|b Woodhead Publishing,
|c 2011.
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|c �1999
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|a 1 online resource (232 pages) :
|b illustrations
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a Horwood Series in Chemical Science
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|a Includes bibliographical references and index.
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|a Online resource; title from PDF title page (ebrary, viewed February 14, 2014).
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|a This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics.
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|a Front Cover; Ions in Solution: Basic Principles of Chemical Interactions; Copyright Page; Table of Contents; Author's preface; List ofsymbols and abbreviations; Chapter 1. Introduction; 1.1 Dissolution of salts; 1.2 Metal ions around the Periodic Table; 1.3 New aqua-metal ions; 1.4 Anions and complexes in solution; 1.5 Model for ions in solution; Chapter 2. Solvation numbers; 2.1 NMR spectroscopy; 2.2 Ion movement methods; 2.3 Review of solvation numbers; Chapter 3. Ion-solvent distances; 3.1 X-ray diffraction by solutions; 3.2 Radial distribution functions.
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|a 3.3 Results of diffraction and scattering studiesChapter 4. Ion-solvent interactions; 4.1 Ultraviolet-visible spectroscopy; 4.2 Infrared and Raman spectroscopy; 4.3 Thermochemistry of ion solvation; Chapter 5. Acid-base behaviour; hydrolysis and polymerisation; 5.1 pK values for aqua-metal ions; 5.2 Polymerisation; 5.3 Anions and ligands; 5.4 Complexes; Chapter 6. Stability constants; 6.1 Definitions; 6.2 Trends; 6.3 Chelates; 6.4 Selectivity; macrocyclic and encapsulating ligands; 6.5 Relevance; Chapter 7. Redox potentials; 7.1 Introduction and thermodynamics; 7.2 Aqua-metal ions.
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|a 7.3 Complexes7.4 Redox potentials and stability constants; Chapter 8. Kinetics and thermodynamics; Chapter 9. Kinetics and mechanisms: solvent exchange; 9.1 Introduction; 9.2 Mechanisms; 9.3 Reactivities; Chapter 10. Kinetics and mechanisms: complex formation; 10.1 Background; 10.2 The Eigen-Wilkins mechanism; 10.3 Chelate formation; 10.4 Polydentate and macrocyclic ligands; 10.5 Crown ethers and cryptands; Chapter 11. Kinetics and mechanisms: substitution at complex ions; 11.1 General; 11.2 Cobalt(III) complexes; 11.3 Platinum(II) complexes; 11.4 Pentacyanoferrates(II); 11.5 Other complexes.
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|a Chapter 12. Kinetics and mechanisms: redox reactions12.1 Introduction; 12.2 The inner-sphere mechanism; 12.3 The outer-sphere mechanism; 12.4 Intermediates, pre-equilibria, and other complications; 12.5 Metal ion oxidation of simple species; 12.6 Oxoanion oxidants; 12.7 lntramolecular electron transfer; Chapter 13. Past, present and future; Glossary; Further reading; Exercises, problems and projects; Index.
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|a Ionic solutions.
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|a Solution (Chemistry)
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|a Ions.
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|a Solutions ioniques.
|0 (CaQQLa)201-0061952
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|a Solutions (Chimie)
|0 (CaQQLa)201-0022536
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|a Ions.
|0 (CaQQLa)201-0004237
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|a solution.
|2 aat
|0 (CStmoGRI)aat300210311
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|a MUSIC
|x Instruction & Study
|x Theory.
|2 bisacsh
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|a Ionic solutions
|2 fast
|0 (OCoLC)fst00978618
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650 |
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|a Ions
|2 fast
|0 (OCoLC)fst00978705
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|a Solution (Chemistry)
|2 fast
|0 (OCoLC)fst01125636
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|i Print version:
|a Burgess, John.
|t Ions in solution : basic principles of chemical interactions.
|d Cambridge, England ; Philadelphia, Pennsylvania ; New Delhi, India : Woodhead Publishing, 2011, �1999.
|b Second edition.
|h 222 pages
|k Horwood Publishing series in chemical science.
|z 9781898563501
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830 |
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|a Horwood Publishing series in chemical science.
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856 |
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|u https://sciencedirect.uam.elogim.com/science/book/9781898563501
|z Texto completo
|