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Ions in solution : basic principles of chemical interactions /

This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Burgess, John
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge, England ; Philadelphia, Pennsylvania ; New Delhi, India : Woodhead Publishing, 2011.
Edición:Second edition.
Colección:Horwood Publishing series in chemical science.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Burgess, John. 
245 1 0 |a Ions in solution :  |b basic principles of chemical interactions /  |c John Burgess. 
250 |a Second edition. 
264 1 |a Cambridge, England ;  |a Philadelphia, Pennsylvania ;  |a New Delhi, India :  |b Woodhead Publishing,  |c 2011. 
264 4 |c �1999 
300 |a 1 online resource (232 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a Horwood Series in Chemical Science 
504 |a Includes bibliographical references and index. 
588 0 |a Online resource; title from PDF title page (ebrary, viewed February 14, 2014). 
520 |a This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughlyEmphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics. 
505 0 |a Front Cover; Ions in Solution: Basic Principles of Chemical Interactions; Copyright Page; Table of Contents; Author's preface; List ofsymbols and abbreviations; Chapter 1. Introduction; 1.1 Dissolution of salts; 1.2 Metal ions around the Periodic Table; 1.3 New aqua-metal ions; 1.4 Anions and complexes in solution; 1.5 Model for ions in solution; Chapter 2. Solvation numbers; 2.1 NMR spectroscopy; 2.2 Ion movement methods; 2.3 Review of solvation numbers; Chapter 3. Ion-solvent distances; 3.1 X-ray diffraction by solutions; 3.2 Radial distribution functions. 
505 8 |a 3.3 Results of diffraction and scattering studiesChapter 4. Ion-solvent interactions; 4.1 Ultraviolet-visible spectroscopy; 4.2 Infrared and Raman spectroscopy; 4.3 Thermochemistry of ion solvation; Chapter 5. Acid-base behaviour; hydrolysis and polymerisation; 5.1 pK values for aqua-metal ions; 5.2 Polymerisation; 5.3 Anions and ligands; 5.4 Complexes; Chapter 6. Stability constants; 6.1 Definitions; 6.2 Trends; 6.3 Chelates; 6.4 Selectivity; macrocyclic and encapsulating ligands; 6.5 Relevance; Chapter 7. Redox potentials; 7.1 Introduction and thermodynamics; 7.2 Aqua-metal ions. 
505 8 |a 7.3 Complexes7.4 Redox potentials and stability constants; Chapter 8. Kinetics and thermodynamics; Chapter 9. Kinetics and mechanisms: solvent exchange; 9.1 Introduction; 9.2 Mechanisms; 9.3 Reactivities; Chapter 10. Kinetics and mechanisms: complex formation; 10.1 Background; 10.2 The Eigen-Wilkins mechanism; 10.3 Chelate formation; 10.4 Polydentate and macrocyclic ligands; 10.5 Crown ethers and cryptands; Chapter 11. Kinetics and mechanisms: substitution at complex ions; 11.1 General; 11.2 Cobalt(III) complexes; 11.3 Platinum(II) complexes; 11.4 Pentacyanoferrates(II); 11.5 Other complexes. 
505 8 |a Chapter 12. Kinetics and mechanisms: redox reactions12.1 Introduction; 12.2 The inner-sphere mechanism; 12.3 The outer-sphere mechanism; 12.4 Intermediates, pre-equilibria, and other complications; 12.5 Metal ion oxidation of simple species; 12.6 Oxoanion oxidants; 12.7 lntramolecular electron transfer; Chapter 13. Past, present and future; Glossary; Further reading; Exercises, problems and projects; Index. 
650 0 |a Ionic solutions. 
650 0 |a Solution (Chemistry) 
650 0 |a Ions. 
650 6 |a Solutions ioniques.  |0 (CaQQLa)201-0061952 
650 6 |a Solutions (Chimie)  |0 (CaQQLa)201-0022536 
650 6 |a Ions.  |0 (CaQQLa)201-0004237 
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650 7 |a Ionic solutions  |2 fast  |0 (OCoLC)fst00978618 
650 7 |a Ions  |2 fast  |0 (OCoLC)fst00978705 
650 7 |a Solution (Chemistry)  |2 fast  |0 (OCoLC)fst01125636 
776 0 8 |i Print version:  |a Burgess, John.  |t Ions in solution : basic principles of chemical interactions.  |d Cambridge, England ; Philadelphia, Pennsylvania ; New Delhi, India : Woodhead Publishing, 2011, �1999.  |b Second edition.  |h 222 pages  |k Horwood Publishing series in chemical science.  |z 9781898563501 
830 0 |a Horwood Publishing series in chemical science. 
856 4 0 |u https://sciencedirect.uam.elogim.com/science/book/9781898563501  |z Texto completo