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SCIDIR_ocn870333919 |
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OCoLC |
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140212s2014 mau o 000 0 eng d |
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|a 1105173292
|a 1105561034
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|a 9780124170346
|q (electronic bk.)
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|a 012417034X
|q (electronic bk.)
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|a (OCoLC)870333919
|z (OCoLC)1105173292
|z (OCoLC)1105561034
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|a QD262
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|a 547.2
|2 23
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|a Roos, Gregory,
|e author.
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|a Key chiral auxiliary applications /
|c Gregory Roos, Murdoch University, Perth, Western Australia.
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|a Second edition.
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|a Waltham, MA :
|b Academic Press,
|c 2014.
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|c �2014
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|a 1 online resource
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a Key Chiral Auxiliary Applications, Second Edition is a detailed compilation of chiral auxiliary applications organized by type of transformation. Continuing from the most important and relevant auxiliaries described in its predecessor, the three-volume set Compendium of Chiral Auxiliary Applications (2001), as well as advances in the field, the book provides a vital and timely resource for chemists in the field. Each reaction class includes a series of tables and graphical abstracts of real reactions from the literature and patents to enable easy review and comparison of results. This anticipated edition is based on a screening of nearly 40,000 auxiliary reaction applications, with details supplied for the more than 13,000 selected representative entries: synthetic route, reagents, yields, diastereomeric/enantiomeric excesses, and characterization data. Updated and streamlined with more than 60% new material, Key Chiral Auxiliary Applications provides valuable guidance and reliable content for selecting the best auxiliary for a specific asymmetric synthetic transformation. Provides a comprehensive compilation based on nearly 40,000 diverse applications of chiral auxiliaries for selecting the best synthetic route to optically pure compoundsContains over 60% new material with 13,000+ auxiliary applications categorized by reaction type, with reaction details and chemical and optical yields in one unique resource.
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|a Front Cover; Key Chiral Auxiliary Applications; Copyright; CONTENTS; ACKNOWLEDGEMENTS; FOREWORD; PREFACE TO THE 2ND EDITION; ABBREVIATIONS; 1. INTRODUCTION; 1.1. BACKGROUND; 1.2. THE CHIRAL AUXILIARY APPROACH; 1.3. THIS COLLECTION; REFERENCES; 2. ALKYLATION AND RELATED REACTIONS I; 2.1 ALLYL AND BENZYL RELATED CARBANIONS; 2.2 ALLENIC ETHER TANDEM ACYLATION-CYCLIZATION; 2.3 ALDEHYDE DERIVED NUCLEOPHILES; 2.4 KETONE DERIVED NUCLEOPHILES; 2.5 ALDEHYDE AND KETONE ENOLATES WITH AUXILIARY-CONTAINING ELECTROPHILES; REFERENCES; 3. ALKYLATION AND RELATED REACTIONS II.
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|a 10. ADDITION TO C=N BONDS10.1 REDUCTION OF IMINES, IMINIUM IONS, HYDRAZONES AND OXIMES; 10.2 NUCLEOPHILIC ADDITION; 10.3 RADICAL ADDITION; 10.4 UGI COUPLING; REFERENCES; 11. ADDITION TO C=O BONDS I; 11.1 REDUCTION; 11.2 WITTIG & RELATED OLEFINATION; 11.3 ADDITION OF ORGANOMETALLIC AND RELATED REAGENTS; REFERENCES; 12. ADDITION TO C=O BONDS II; 12.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); REFERENCES; 13. ADDITION TO C=O BONDS III; 13.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); 13.2 TANDEM REACTIONS; 13.3 RADICAL REACTIONS; REFERENCES; 14. CYCLOADDITIONS I.
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|a Asymmetric synthesis.
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|a Enantioselective catalysis.
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|a Enantiomers.
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|a Synth�ese asym�etrique.
|0 (CaQQLa)201-0242091
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|a Catalyse �enantios�elective.
|0 (CaQQLa)201-0353989
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|a �Enantiom�eres.
|0 (CaQQLa)201-0057866
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650 |
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|a Asymmetric synthesis
|2 fast
|0 (OCoLC)fst00819861
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650 |
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|a Enantiomers
|2 fast
|0 (OCoLC)fst00909487
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650 |
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|a Enantioselective catalysis
|2 fast
|0 (OCoLC)fst00909493
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|u https://sciencedirect.uam.elogim.com/science/book/9780124170346
|z Texto completo
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