Advances in inorganic chemistry. Volume 65, Homogeneous catalysis /

The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves a...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Eldik, Rudi van, Hubbard, Colin D.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Waltham, MA : Academic Press, 2013.
Colección:Advances in inorganic chemistry ; 65
Temas:
Chemistry, Inorganic.
Catalysis.
Chemistry, Inorganic
Catalysis
Chimie inorganique.
Catalyse.
inorganic chemistry.
SCIENCE > Chemistry > Physical & Theoretical.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • 2.2. Manganese complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands3. Cellulosic Bleaching; 3.1. Detergent applications; 3.1.1. General; 3.1.2. Activation of hydrogen peroxide by transition-metal complexes; 3.1.3. Stain bleaching by manganese complexes with 1,4,7-triazacyclononane-based ligands; 3.2. Raw cotton bleaching; 3.2.1. General; 3.2.2. Manganese complexes containing 1,4,7-triazacyclononane ligands; 3.3. Wood pulp bleaching; 3.3.1. General; 3.3.2. Bleach catalysts; 4. Paint Drying; 5. Conclusions; References
  • Chapter Four: Green Challenges of Catalysis via Iron(IV)oxo and Iron(V)oxo Species1. Introduction; 2. Iron(IV)oxo Complexes; 3. A Race for Iron(V)oxo Molecules; 3.1. Spectral characterization of iron(V)oxo compounds; 3.2. Reactivity of iron(V)oxo complexes; 4. Oxidative Catalysis in Aqueous Environment; 4.1. Guiding strategies; 4.2. Catalyzed oxidations by hydrogen peroxide in water; 4.3. Second generation of TAML activators; 4.4. Problems associated with environmentally relevant catalysis; 4.5. Novel applications of TAML activators
  • 5. Back to Nature or Metal-Organic Framework Instead of a Protein Coat?5.1. Protection of oxidation catalyst by biomolecules; 5.2. Metal-organic materials; 6. Concluding Remarks; Acknowledgments; References; Chapter Five: Manganese Compounds as Versatile Catalysts for the Oxidative Degradation of Organic Dyes; 1. Introduction; 2. Metal Ion-Catalyzed Oxidative Dye Degradation by H2O2; 2.1. General observations; 2.2. Complex formation between bicarbonate and Mn(II); 2.3. Complex formation between dye and Mn(II); 2.4. Mn(II)+H2O2/HCO3-: Intermediates in the absence of dye substrate

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