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Introduction to fluoropolymers : materials, technology, and applications /

Introduction to Fluoropolymers demystifies fluoropolymers for a wide audience of designers, engineers, sales staff and managers. This important group of high-performance polymers has applications across a wide range of market sectors, including automotive, aerospace, medical devices, high performanc...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Ebnesajjad, Sina
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; Boston : Elsevier Science & Technology, 2013.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Machine generated contents note: References
  • 2.1. Uniqueness of Fluorine
  • 2.2. Fluorine Characteristics
  • 2.2.1. Fluorination
  • 2.2.2. Reactivity: An Extreme Element
  • 2.2.3. Preparation of Fluorine
  • 2.2.4. Inorganic Chemistry
  • 2.2.5.Organic Chemistry
  • 2.2.6. Fluorine and Nature
  • References
  • 3.1.Coming of Age of Polymer Science
  • 3.2. Roy Plunkett's Story
  • 3.3.Commercialization of PTFE
  • 3.4. What are Fluoropolymers?
  • 3.5. Fundamental Properties of Fluoropolymers
  • 3.6. Developmental History of Fluoropolymers
  • 3.7. Fluoropolymer Consumption and Use
  • 3.8. Examples of Uses of Fluoropolymers
  • References
  • Further Reading
  • 4.1. Early History of W.L. Gore and Associates
  • 4.2. Discovery of Expanded PTFE
  • 4.3. Who Invented ePTFE?
  • 4.4. Other ePTFE Players
  • References
  • 5.1. Introduction
  • 5.2. Polyvinyl Fluoride
  • 5.2.1. History
  • 5.2.2. Development of Polyvinyl Fluoride
  • References
  • 6.1. Introduction
  • 6.2. Fluoropolymer Classification
  • 6.3. Fluoropolymer Products
  • 6.4. Monomer Synthesis
  • 6.4.1. Synthesis of Tetrafluoroethylene
  • 6.4.2. Synthesis of Hexafluoropropylene
  • 6.4.3. Synthesis of Perfluoroalkyl Vinyl Ethers
  • 6.4.4. Synthesis of Chlorotrifluoroethylene
  • 6.4.5. Synthesis of Vinylidene Fluoride
  • 6.4.6. Synthesis of Vinyl Fluoride
  • 6.5. Monomer Properties
  • 6.5.1. Properties of Tetrafluoroethylene
  • 6.5.2. Properties of Hexafluoropropylene
  • 6.5.3. Properties of Perfluoroalkyl Vinyl Ethers
  • 6.5.4. Properties of Chlorotrifluoroethylene
  • 6.5.5. Properties of Vinylidene Fluoride
  • 6.5.6. Properties of Vinyl Fluoride
  • 6.6. Polymerization and Finishing
  • 6.6.1. Polytetrafluoroethylene, PTFE (CAS number 9002-84-0)
  • 6.6.2. Perfluoroalkoxy Polymer, PFA (CAS number 26655-00-5)
  • 6.6.3. Perfluorinated Ethylene Propylene Copolymer, FEP (CAS number 25067-11-2)
  • 6.6.4. Ethylene tetrafluoroethylene Copolymers, ETFE (CAS number 68258-85-5)
  • 6.6.5. Ethylene chlorotrifluoroethylene Copolymers, ECTFE (CAS number 25101-45-5)
  • 6.6.6. Polychlorotrifluoroethylene, PCTFE (CAS number 9002-83-9)
  • 6.6.7. Polyvinylidene Fluoride, PVDF (CAS number 24937-79-9)
  • 6.6.8. Polyvinyl Fluoride, PVF (CAS number 24981-14-4)
  • 6.7. Structure Property Relationship
  • 6.8. Polymer Properties
  • 6.8.1. PTFE Properties
  • 6.8.2. PFA Properties
  • 6.8.3. FEP Properties
  • 6.8.4. PCTFE Properties
  • 6.8.5. EPFE Properties
  • 6.8.6. ECTFE Properties
  • 6.8.7. PVDF Properties
  • 6.8.8. PVF Properties
  • 6.9. Fabrication Techniques
  • 6.10. Applications
  • 6.11. Safety
  • 6.12. Ammonium Perfluorooctanoate (APFO, also C8)
  • 6.13. Economy
  • 6.14. Summary
  • References
  • Bibliography
  • 7.1. Introduction
  • 7.2. Tetrafluoroethylene (TFE) Preparation
  • 7.3. Properties of Tetrafluoroethylene
  • 7.4. Polymerization of Tetrafluoroethylene
  • 7.5. Tetrafluoroethylene Polymers
  • 7.5.1. Ammonium Perfluorooctanoate (APFO, also C8)
  • 7.6. Polymerization Mechanism
  • 7.7. Suspension Polymerization of Tetrafluoroethylene
  • 7.7.1. Finishing Technologies of Granular PTFE
  • 7.8. Emulsion Polymerization of Tetrafluoroethylene
  • 7.8.1. Dispersion Products
  • 7.8.2. Fine Powder (Coagulated Dispersion) Products
  • 7.9. Characterization of Polytetrafluoroethylene
  • 7.9.1. Granular PTFE Resins
  • 7.9.2. Fine Powder PTFE Resins
  • 7.9.3. Dispersions of PTFE
  • References
  • 8.1. Polymeric Fluorinated Additives
  • 8.1.1. Polytetrafluoroethylene Homopolymer Additives
  • 8.1.2. Fluoroelastomer Additives (Polymer Processing Additives)
  • 8.1.3. Vinylidene Fluoride Polymer Additives
  • 8.2. Perfluoropolyether (PFPE) Additives
  • 8.3. PTFE Modified Waxes
  • 8.4. Fluorinated Graphite
  • 8.5. Fluorination
  • References
  • 9.1. Synthesis of Vinylidene Fluoride
  • 9.1.1. Conversion of 1,1,1-trifluoroethane
  • 9.1.2.Commercial Process
  • 9.2. Preparation of Vinylidene Fluoride Polymers
  • 9.2.1. Emulsion Polymerization of Vinylidene Fluoride
  • 9.2.2. Suspension Polymerization of Vinylidene Fluoride
  • 9.2.3. Solution Polymerization of Vinylidene Fluoride
  • 9.3. Characterization of Polyvinylidene Fluoride (PVDF)
  • 9.4. Properties of Polyvinylidene Fluoride
  • 9.4.1. Conformations and Transitions of Polyvinylidene Fluoride
  • 9.5. Processing Polyvinylidene Fluoride
  • 9.6. Applications
  • References
  • 10.1. Introduction / Jiri George Drobny
  • 10.2. Fluorocarbon Elastomers / Jiri George Drobny
  • 10.2.1. Manufacturing Process / Jiri George Drobny
  • 10.2.2. Properties Related to the Polymer Structure / Jiri George Drobny
  • 10.2.3. Cross-Linking Chemistry / Jiri George Drobny
  • 10.2.4. Formulation of Compounds from Fluorocarbon Elastomers / Jiri George Drobny
  • 10.2.5. Mixing and Processing of Compounds from Fluorocarbon Elastomers / Jiri George Drobny
  • 10.2.6. Solution and Latex Coating / Jiri George Drobny
  • 10.2.7. Curing / Jiri George Drobny
  • 10.2.8. Physical and Mechanical Properties of Cured Fluorocarbon Elastomers / Jiri George Drobny
  • 10.2.9. Applications of FKMs / Jiri George Drobny
  • 10.2.10. Applications of FFKMs / Jiri George Drobny
  • 10.2.11. Applications of FKMs in Coatings and Sealants / Jiri George Drobny
  • 10.2.12. Applications of FKMs as Polymeric Processing Additives / Jiri George Drobny
  • 10.3. Fluorosilicone Elastomers / Jiri George Drobny
  • 10.3.1. Polymerization / Jiri George Drobny
  • 10.3.2. Processing / Jiri George Drobny
  • 10.3.3. Properties of Cured Fluorosilicones / Jiri George Drobny
  • 10.3.4. Applications of Fluorosilicone Elastomers / Jiri George Drobny
  • 10.4. Fluorinated Thermoplastic Elastomers / Jiri George Drobny
  • 10.4.1. Applications of Fluorinated Thermoplastic Elastomers / Jiri George Drobny
  • 10.5. Phosphazenes / Jiri George Drobny
  • 10.6. Safety, Hygiene, and Disposal / Jiri George Drobny
  • 10.6.1. Polymerization and Finishing / Jiri George Drobny
  • 10.6.2.Compounding, Mixing, and Processing / Jiri George Drobny
  • 10.6.3. Hazardous Conditions during Use / Jiri George Drobny
  • 10.6.4. Disposal of Used Products / Jiri George Drobny
  • 10.7. New Developments and Current Trends / Jiri George Drobny
  • 10.7.1. New Developments in Chemistry and Processing / Jiri George Drobny
  • 10.7.2. New Products / Jiri George Drobny
  • 10.7.3. Other Developments / Jiri George Drobny
  • Acronyms and Abbreviations / Jiri George Drobny
  • Glossary of Terms / Jiri George Drobny
  • References / Jiri George Drobny
  • Bibliography / Jiri George Drobny
  • 11.1. Introduction / Laurence W. McKeen
  • 11.2. Fluoropolymers Used in Coatings / Laurence W. McKeen
  • 11.2.1. Polytetrafluoroethylene (PTFE) / Laurence W. McKeen
  • 11.2.2. Fluorinated Ethylene Propylene (FEP) Copolymer / Laurence W. McKeen
  • 11.2.3. Perfluoroalkoxy (PFA) Polymers / Laurence W. McKeen
  • 11.2.4. Ethylene Tetrafluoroethylene (ETFE) Copolymers / Laurence W. McKeen
  • 11.2.5. Polyvinylidene Fluoride (PVDF) / Laurence W. McKeen
  • 11.2.6. Ethylene Chlorotrifluoroethylene (ECTFE) Copolymer / Laurence W. McKeen
  • 11.3. Fluorocoating Compositions / Laurence W. McKeen
  • 11.3.1. Fluoropolymer / Laurence W. McKeen
  • 11.3.2. Pigments and Fillers / Laurence W. McKeen
  • 11.3.3. Solvents / Laurence W. McKeen
  • 11.3.4. Additives / Laurence W. McKeen
  • 11.3.5. Nonfluoropolymer Binders / Laurence W. McKeen
  • 11.3.6. Liquid and Powder Coatings / Laurence W. McKeen
  • 11.3.7. Liquid Coatings / Laurence W. McKeen
  • 11.3.8. Powder Coatings / Laurence W. McKeen
  • 11.4. Application of Fluorocoatings / Laurence W. McKeen
  • 11.4.1. Substrate / Laurence W. McKeen
  • 11.4.2. Liquid Coating / Laurence W. McKeen
  • 11.4.3. Powder Coating / Laurence W. McKeen
  • 11.4.4. Baking/Curing / Laurence W. McKeen
  • 11.5.Commercial Fluorocoating Producers / Laurence W. McKeen
  • 11.6.A Historical Chronology of Fluoropolymer Finish Technology / Laurence W. McKeen
  • 11.7. Food Contact / Laurence W. McKeen
  • 11.8.Commercial Applications of Fluorocoatings / Laurence W. McKeen
  • 11.8.1.
  • Housewares: Cookware, Bakeware, Small Electrical Appliances (SEAs) / Laurence W. McKeen
  • 11.8.2.Commercial or Industrial Bakeware / Laurence W. McKeen
  • 11.8.3. Fuser Rolls / Laurence W. McKeen
  • 11.8.4. Light Bulbs / Laurence W. McKeen
  • 11.8.5. Automotive / Laurence W. McKeen
  • 11.8.6. Chemical Processing Industry (CPI) / Laurence W. McKeen
  • 11.8.7.Commercial Dryer Drums / Laurence W. McKeen
  • 11.8.8. Industrial Rollers / Laurence W. McKeen
  • 11.8.9. Medical Devices / Laurence W. McKeen
  • 11.9. Summary / Laurence W. McKeen
  • References / Laurence W. McKeen
  • 12.1. History / Walther Grot
  • 12.2.Composition / Walther Grot
  • 12.3. Properties / Walther Grot
  • References / Walther Grot
  • 13.1. Introduction / Walther Grot
  • 13.2. Toxicology of Fluoropolymers / Walther Grot
  • 13.3. Thermal Properties of Fluoropolymers / Walther Grot
  • 13.4. Emission During Processing / Walther Grot
  • 13.5. Safety Measures / Walther Grot
  • 13.5.1. Ventilation / Walther Grot
  • 13.5.2. Processing and Fabrication / Walther Grot
  • 13.5.3. Spillage Cleanup / Walther Grot
  • 13.5.4. Equipment Cleaning and Maintenance / Walther Grot
  • 13.5.5. Protective Clothing / Walther Grot
  • 13.5.6. Personal Hygiene / Walther Grot
  • 13.5.7. Fire Hazard / Walther Grot
  • 13.5.8. Material Incompatibility / Walther Grot
  • 13.6. Food Contact and Medical Applications / Walther Grot
  • 13.7. Fluoropolymer Scrap and Recycling / Walther Grot
  • 13.8. Environmental Protection and Disposal Methods / Walther Grot
  • References / Walther Grot.