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Reactions in condensed phases /
Reaction In Condensed Phases.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Academic Press,
1975.
|
| Colección: | Physical chemistry, an advanced treatise ;
v. 7. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Physical Chemistry: An Advanced Treatise: Reactions in Condensed Phases; Copyright Page; Table of Contents; List of Contributors; Foreword; Preface; Contents of Previous and Future Volumes; Chapter 1. Theory of Reaction Rates in Condensed Phases; I. Introduction; II. Quantum Theory of Unimolecular Rate Processes; III. Effect of Diffusion on the Rate of Reactions; IV. Reaction-Controlled Kinetics; V. Quenching (or Energy Transfer) of Luminescence; Acknowledgements; References; Chapter 2. Methods for the Estimation of Rate Parameters of Elementary Processes; I. Introduction.
- II. Definitions and RelationshipsIII. Estimation of Thermochemical Quantities; IV. Rate Parameters for Unimolecular Processes; V. Rate Parameters for Bimolecular Processes; VI. Effects of Solvents; References; Chapter 3. Use of Correlation Diagrams for Interpretation of Organic Reactivity; I. Introduction; II. Simple MO Theory; III. Correlation Diagrams; IV. Substituent Effects on Correlation Diagrams; V. Concerted and Nonconcerted Thermal Reactions; VI. Pericyclic Reactions; VII. Nonconcerted Analogs of Pericyclic Reactions; VIII. Photochemical Reactions; IX. Chemiluminescent Reactions.
- X. SummaryAcknowledgements; References; Chapter 4. Perturbation of Reactions by Substituents; I. Definition of Substituent Effects; II. Substituent Effects on Free Energies; III. Some Classical Interaction Mechanisms; IV. Common Linear Free Energy Relationships and Their Parameters; V. Effects of Multiple Interactions; VI. The Role of Potential Energy, Enthalpy, and Entropy; VII. Concluding Remarks; References; Chapter 5. Mechanisms of Inorganic Reactions in Solution; I. Introduction; II. The Classification of Mechanisms for Nucleophilic Substitution.
- III. Labile Complexes in Aqueous SolutionIV. Substitution on Inert Octahedral Complexes; V. Octahedral Racemization and the Stereochemistry of Octahedral Substitution; VI. Substitution on Platinum (II) Complexes; VII. Electron Transfer Reactions of Complex Ions; Special References; Chapter 6. Kinetics of Free-Radical Reactions; I. Introduction; II. Kinetic Characteristics of Chain Reactions; III. Derivations of Steady-State Rate Laws; IV. Absolute Reaction Rate Data; V. Competition Kinetics; VI. Solvent Effects; References; Chapter 7. Heterogeneous Catalysis.
- I. General Kinetic Relations: The Single ReactionII. Kinetics of Elementary Processes; III. Kinetics on Nonuniform Surfaces; IV. Networks of Reactions; Acknowledgements; List of Symbols; References; Chapter 8. Reactions at Surfaces; I. Introduction; II. Pourbaix Diagrams; III. Reactions at Metal-Solution Interfaces; IV. Reactions at Nonmetal-Solution Interfaces; References; Chapter 9. Chemical Annealing Reactions in Solids; I. Production of Systems; II. Production Not Involving Bond Rupture; III. Production with Bond Rupture; IV. Kinetic Analysis of the Annealing Data.