Chain Structure and Conformation of Macromolecules /
Chain Structure and Conformation of Macromolecules.
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Oxford :
Elsevier Science,
1982.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Chain Structure and Conformation of Macromolecules; Copyright Page; Table of Contents; Preface; Chapter 1. The Structure of Polymer Chains; 1.1 Introduction; 1.2 History of the Macromolecular Concept; 1.3 Isomerism in Vinyl Polymer Chains; 1.4 Isomerism in Diene Polymer Chains; 1.5 Vinyl Polymers with Optically Active Side Chains; 1.6 Polymers with Asymmetric Centers in the Main; 1.7 Other Types of Isomerism; References; Chapter 2. The Spectroscopy of Macromolecules; 2.1 Introduction; 2.2 Vibrational Spectroscopy; 2.3 Nuclear Magnetic Resonance Spectroscopy; General References.
- Chapter 3. Stereochemical Configuration and Its Observation3.1 Introduction; 3.2 Model Compounds for Vinyl Polymer Chains; 3.3 Polymer Chains; 3.4 The Effect of Polymerization Temperature on Stereochemical Configuration; 3.5 More Complex Proton Spectra; Computer Simulation; 3.6 Carbon-13 Spectroscopy; 3.7 Fluorine Spectroscopy; Appendix; References; Chapter 4. Geometrical Isomerism in Diene Polymers; 4.1 Introduction; 4.2 Polybutadiene; 4.3 Polyisoprene; 4.4 Polychloroprene; References; Chapter 5. Copolymerization and Copolymer Structure; 5.1 Introduction; 5.2 Copolymer Composition.
- The Copolymer Equation5.3 Reactivity Ratios; 5.4 Determination of Reactivity Ratios; 5.5 Monomer Sequences and Their Observation; References; Chapter 6. Regioregularity and Branching in Vinyl Polymer Chains; 6.1 Introduction; 6.2 Head-To-Tail Versus Head-To-Head:Tail-To-Tail Isomerism; Regioregularity; 6.3 Branching in Vinyl Polymers; References; Chapter 7. Chain Conformations of Macromolecules; 7.1 Introduction; 7.2 The Freely Jointed Chain; 7.3 The Freely Rotating Chain; 7.4 Chains with Restricted Rotation; 7.5 Experimental Observation of Polymer Chain Conformations in Solution.
- 7.6 Experimental Observation of Polymer Chain Conformations in the Crystalline State7.7 Experimental Observation of Polymer Chain Conformations in the Amorphous Solid State; 7.8 Chain Conformation and Chemical Shift; References; General References; Chapter 8. Solid State NMR of Macromolecules; 8.1 Introduction; 8.2 Pulsed Fourier Transform Nmr and Relaxation; 8.3 Dipolar Broadening in Solids; 8.4 High Power Proton Decoupling; 8.5 Chemical Shift Anisotropy; 8.6 Magic Angle Spinning; 8.7 1H-13C Cross Polarization; 8.8 Solid State Carbon-13 NMR of Polymers; References; Index.