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Polyacetylene : Chemistry, Physics, and Material Science.
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford :
Elsevier Science,
1984.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Polyacetylene: Chemistry, Physics, and Material Science; Copyright Page; Dedication; Table of Contents; Preface; Chapter 1. Introduction; 1.1 Synthetic Polymers; 1.2 Energy Bands; 1.3 Metals, Semiconductors, and Insulators; 1.4 Semimetals: Dimensionality; 1.5 Charge-Transfer Salts; 1.6 Organic Conductive Polymers; 1.7 Polyacetylene; Chapter 2. Polymerization; 2.1 Introduction; 2.2 Polymerization of Acetylene Catalyzed by Ti(OBu)4-AlEt3; 2.3 Polymerization of Acetylene by the Luttinger Catalyst; 2.4 Methylacetylene Homo- and Copolymers; 2.5 Polymerization Mechanism.
- 2.6 Molecular Weight Determination2.7 Kinetics; 2.8 Comparison of Various Catalyst Systems; 2.9 Graft and Block Copolymers; Chapter 3. Structures; 3.1 Introduction; 3.2 Geometric Isomerism; 3.3 Chain Regularity; 3.4 Degree of Crystallinity; 3.5 Crystal Structure of cis-Polyacetylene; 3.6 Crystal Structure of trans-Polyacetylene; 3.7 Bond-Length Alternation; 3.8 Thermal Isomerization and Crystal Structure Change; 3.9 Crystal Structure of Diblock Copolymers of Styrene and Acetylene; Chapter 4. Morphology; 4.1 Introduction; 4.2 Fibrils and Microfibrils.
- 4.3 Globular Morphology and Effect of Heat of Polymerization4.4 Lamellar Morphology; 4.5 Whiskerlike Ribbon Crystal Morphologies; 4.6 Mechanically Aligned Polyacetylenes; 4.7 Surface Areas; Chapter 5. Isomerization, Neutral Defects, and Solitons; 5.1 Introduction; 5.2 Thermal Isomerization; 5.3 Doping-Induced Isomerization; 5.4 Electron Paramagnetic Resonance and Neutral Defects; 5.5 Spin Dynamics; 5.6 Mechanisms of Soliton Formation and of Cis-Trans Isomerization; Chapter 6. Spectroscopic, Physical, and Mechanical Properties; 6.1 Vibrational Spectra; 6.2 Optical Absorption and Reflections.
- 6.3 Photoexcitation, Luminescence, and Photoconductivity6.4 Heat Capacity; 6.5 Thermal Conductivity; 6.6 Tensile Properties; 6.7 Dielectric Constants; 6.8 Proton Nuclear Magnetic Resonance; 6.9 Carbon-13 Nuclear Magnetic Resonance; Chapter 7. Chemical Reactions; 7.1 Thermochemistry; 7.2 Reactions with Hydrogen; 7.3 Reaction with Bromine; 7.4 Reaction with Ozone; 7.5 Reaction with Oxygen; 7.6 Cross-linking; Chapter 8. Doping; 8.1 Introduction; 8.2 Doping Methods; 8.3 Dopants and the Nature of Dopant Species; 8.4 Doping of eis- and trans-Polyacetylenes; 8.5 Diffusion of Dopants.
- 8.6 Compensation8.7 Effect of Doping on Morphology; 8.8 Mechanisms of Doping; Chapter 9. Conducting Polyacetylene; 9.1 Introduction; 9.2 Crystal Structure; 9.3 Magnetic Susceptibilities; 9.4 Visible and Infrared Absorptions; 9.5 Nuclear Magnetic Resonance; 9.6 Specific Heats; 9.7 Photoelectron Spectra; 9.8 Stability; Chapter 10. Theoretical Models; 10.1 Band Structure; 10.2 Microscopic Discrete Model for a Neutral Soliton; 10.3 Continuum Model; 10.4 Coulombic Interaction and Correlation Effect; 10.5 Properties of Solitons; 10.6 Polaron; Chapter 11. Electrical Properties.