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Handbook on the physics and chemistry of rare earths : including actinides. Volume 43 /

The rare earths represent a group of chemical elements, the lanthanides, together with scandium and yttrium, which exhibit similar chemical properties. They are strategically important to developed and developing nations as they have a wide variety of applications in catalysis, the defense industry,...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Pecharsky, Vitalij K., B�unzli, Jean-Claude G.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Elsevier, 2013.
Colección:Handbook on the physics and chemistry of rare earths ; v. 43.
Temas:
Acceso en línea:Texto completo
Texto completo
Tabla de Contenidos:
  • 7. Bis(benzimidazolyl)pyridine Complexes8. Phthalocyanine Complexes; 9. Porphyrin Complexes; 10. Lanthanide Alkanoates; 11. Polyoxometalate-Surfactant Complexes; 12. Miscellaneous Thermotropic Lanthanidomesogens; 13. Lyotropic Lanthanidomesogens; 14. Physical Properties; 14.1. Luminescence; 14.2. Magnetism; 14.3. Electrical Properties; 15. Actinidomesogens; 16. Conclusions and Outlook; Abbreviations; References; Chapter 255: Recycling of Rare Earths from Scrap; 1. Introduction; 2. Permanent Magnets; 2.1. Physical Separation; 2.1.1. Demagnetization; 2.1.2. Hard Disk Drives
  • 2.1.3. Air-Conditioner Compressors2.1.4. Separation from DD Motors in Laundry Machines; 2.2. Hydrometallurgical Methods; 2.2.1. Sm-Co Magnets; 2.2.2. Nd-Fe-B Magnets; 2.2.2.1. Fractional Crystallization Method; 2.2.2.2. Whole Leaching Process; 2.2.2.3. Selective Roasting-Leaching; 2.2.2.4. Selective Leaching; 2.2.2.5. Hydrothermal Method; 2.2.2.6. Solvent Extraction and Related Techniques; 2.2.3. Mixture of Sm-Co and Nd-Fe-B Magnets; 2.3. Pyrometallurgical Methods; 2.3.1. Methods Using Gas-Solid and Solid-Liquid Reactions; 2.3.2. Methods Using Molten Salts; 2.3.2.1. Electrochemical Process
  • 2.3.2.2. Flux or Slag Process2.4. Pyrolysis of Epoxy-Resin-Bonded Magnet; 3. Phosphors; 3.1. Physical Separation; 3.1.1. Recovery of Mixed Rare-Earth Phosphors; 3.1.1.1. Dry Separation Process; 3.1.1.2. Wet Separation Process; 3.1.1.3. Selective Crushing for Bulb-Type Fluorescent Lamps; 3.1.2. Recovery of Individual Rare-Earth Phosphors; 3.2. Hydrometallurgical Methods; 3.2.1. Direct Leaching; 3.2.2. Mechanochemical Treatment; 3.2.3. Alkaline Fusion; 3.2.4. Separation by Solvent Extraction and Its Related Technique; 4. Batteries; 4.1. Physical Separation; 4.2. Hydrometallurgical Methods
  • 4.2.1. H2SO4 System4.2.2. HCl System; 4.3. Molten Salt Electrolysis; 5. Polishing Powders, Optical Glass, and Catalysts; 5.1. Polishing Powders; 5.2. Optical Glass; 5.3. Catalysts; 6. Concluding Remarks; Abbreviations; References; Chapter 256: Ionic Liquids: New Hopes for Efficient Lanthanide/Actinide Extraction and Separation?; 1. Introduction; 2. Ionic Liquids: Some Facts and Figures; 3. Liquid-Liquid Extraction of Rare Earths and Actinides; 3.1. Traditional Organic Solvents: A Brief Overview; 3.2. Extraction Processes in Nuclear Industry