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The porphyrins. Volume 3, Physical chemistry. Part A /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Dolphin, David
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York : Academic Press, 1978.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; The Porphyrins V3: Physical Chemistry, Part A; Copyright Page; Table of Contents; List of Contributors; General Preface; Preface; Contents of Other Volumes; Chapter 1. Optical Spectra and Electronic Structure of Porphyrins and Related Rings; I. Scope of Chapter; II. Regular Porphyrins [Groups I-V-Valence I-V, respectively; Th(IV); U(VI)]; III. Irregular Porphyrins; IV. Theory; References; Chapter 2. Electronic Absorption Spectra of Hemes and Hemoproteins; I. Introduction; II. Description of Porphyrin Spectra; III. Theoretical Description of Porphyrin Spectra
  • IV. Theoretical Description of Iron PorphyrinsV. Heme Proteins; VI. Summary; References; Chapter 3. Electronic Absorption Spectra of Chlorophylls; I. Molecular Orbital Theory of Chlorophylls; II. Phenomenology and Comparison with Theory; III. Further Applications of Molecular Orbital Theory of Chlorophylls; References; Chapter 4. The Magnetic Optical Activity of Porphyrins; I. Introduction; II. The Phenomena; III. Classification of Porphyrins by Spectral Type; IV. Zero Field Splitting; V. Instrumentation; References; Chapter 5. The Magnetic Optical Activity of Hemoproteins; I. Introduction
  • II. Magnetic Optical Activity: The Faraday EffectIII. Sensitivity to the Chemistry of Iron; IV. Effects of Protein Environment; V. Microparticulate Heme Proteins; VI. Lanthanide-Substituted Porphyrins; References; Chapter 6. Circular Dichroism Studies of Hemoproteins and Heme Models; I. Introduction; II. Definitions; III. Electronic Configuration and Absorption Properties of Heme Systems; IV. Protein Optical Activity: Theory and Analysis; V. Heme Optical Activity: Origin and Analysis; VI. CD Spectra of Selected Examples; References; Chapter 7. Infrared Spectroscopy of Porphyrins
  • I. IntroductionII. Sampling Considerations; III. Band Assignments; IV. Trans-Ligand Structure of Heme Protein Complexes; V. Polarizability of Metal-Porphyrin Complexes; VI. Cis and Trans Effects; VII. Nonpolar Interactions and Molecular Pairs in Heme Proteins; References; Chapter 8. Resonance Raman Scattering from Metalloporphyrins and Hemoproteins; I. Introduction; II. Experimental Techniques; III. Theory; IV. Metalloporphyrin Resonance Raman Spectra; References; Chapter 9. Mass Spectra of Porphyrins and Related Compounds; I. General Remarks; II. Porphine Derivatives; III. Corrins
  • IV. HomoporphyrinsV. Heteraporphine and Heteracorrin Derivatives; VI. Concluding Remarks; References; Chapter 10. Porphyrin Stereochemistry; I. Introduction; II. Metalloporphyrin Stereochemistry; III. Stereochemistry of Metal-Free Porphyrins; IV. Addendum; References; Chapter 11. A Photographic Essay of Porphyrins and Related Macrocycles; Text; References; Chapter 12. High-Resolution Zeeman Spectroscopy of Metalloporphyrins; I. Introduction; II. Zeeman Effect in Metalloporphyrins; References; Author Index; Subject Index