Cargando…
Writing reaction mechanisms in organic chemistry /
Presentation is clear and instructive: students will learn to recognize that many of the reactions in organic chemistry are closely related and not independent facts needing unrelated memorization. The book emphasizes that derivation of a mechanism is not a theoretical procedure, but a means of appl...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
[Place of publication not identified] :
Academic Press,
1992.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Table of Contents; Preface; Chapter 1. Introduction; 1-1 Writing Structures for Organic Compounds; 1-2 Electronegativities and Dipoles; 1-3 Resonance Structures and Aromaticity; 1-4 Equilibrium and Tautomerism; 1-5 Acidity and Basicity; 1-6 Nucleophiles and Electrophiles; Answers to Problems; Chapter 2. General Principles for Writing Organic Mechanisms; Answers to Problems; Chapter 3. Reactions of Nucleophiles and Bases; 3-1 Nucleophilic Substitution; 3-2 Other Elimination Reactions
- 3-3 Nucleophilic Addition to Carbonyl Compounds3-4 Base-Promoted Rearrangements; 3-5 Reaction Mechanisms in Basic Media; Answers to Problems; Chapter 4. Reactions Involving Acids and Other Electrophiles; 4-1 Carbocations; 4-2 Electrophilic Addition; 4-3 Acid-Catalyzed Reactions of Carbonyl Compounds; 4-4 Electrophilic Aromatic Substitution; 4-5 Carbenes, Nitrenes and Nitrenium Ions; Answers to Problems; Chapter 5. Radicals and Radical Anions; 5-1 Introduction; 5-2 Formation of Radicals; 5-3 Radical Chain Processes; 5-4 Radical Inhibitors and Chain Transfer Agents
- 5-5 Determination of Thermodynamic Feasibility of Radical Reactions5-6 Addition of Radicals; 5-7 Fragmentation Reactions; 5-8 Rearrangement of Radicals; 5-9 The SRN1 Reaction; 5-10 The Birch Reduction; 5-11 A Radical Mechanism for the Rearrangement of Some Anions; Answers to Problems; Chapter 6. Pericyclic Reactions; 6-1 Introduction; 6-2 Representations of Molecular Orbitals; 6-3 A General Method to Predict Whether a Reaction is Symmetry Allowed or Symmetry Forbidden; 6-4 Electrocyclic Reactions; 6-5 Cycloadditions; 6-6 Sigmatropic Reactions; 6-7 The Ene Reaction; Answers to Problems
- Chapter 7. A Mixed Bag-Additional ProblemsAnswers to Problems; Index