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Organic photochemistry : principles and applications /
Organic Photochemistry outlines the principles, techniques and well-known reactions occurring in organic molecules and also illustrates more complex photochemical transformations occurring in organic chemistry. Many photochemical transformations convert simple molecules into extremely complex produc...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
[Place of publication not identified] :
Academic Press,
1993.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Organic Photochemistry: Principles and Applications; Copyright Page; Table of Contents; Preface; Chapter 1. The fundamentals; 1.1. WHAT IS PHOTOCHEMISTRY?; 1.2. PHOTOCHEMISTRY: BASIC PRINCIPLES; 1.3. ACTION SPECTRA; 1.4. ABSORPTION OF LIGHT AND MOLECULAR ORBITALS; 1.5. SINGLET AND TRIPLET STATES OF MOLECULES; 1.6. FATE OF ELECTRONICALLY EXCITED MOLECULES; 1.7. MAKING INTERSYSTEM CROSSING MORE EFFICIENT: THE HEAVY-ATOM EFFECT; 1.8. TIME SCALE; 1.9. RELATIONSHIP BETWEEN WAVELENGTH AND PHOTON ENERGY; 1.10. UNITS; 1.11. BEER-LAMBERT'S LAW
- 1.12. SOLVENT DEPENDENCE OF ABSORPTION SPECTRA SOLVATOCHROMIC DYES; 1.13. SOLVENT, TEMPERATURE, AND CONCENTRATION DEPENDENCE OF LUMINESCENCE SPECTRA; 1.14. WAVELENGTH DEPENDENCE OF PHOTOCHEMICAL REACTIONS; 1.15. QUANTUM YIELDS; 1.16. QUANTUM YIELDS AND CHEMICAL YIELDS; 1.17. ACTINOMETERS; 1.18. PHOTOSENSITIZED REACTIONS; 1.19. MECHANISTIC STUDIES; 1.20. PHOTOSENSITIZED REACTIONS OF A TRIPLET GROUND STATE MOLECULE; 1.21. EXPERIMENTAL CONSIDERATIONS FOR PHOTOSENSITIZED REACTIONS; 1.22. KINETICS; 1.23. ELECTRONICALLY EXCITED MOLECULES FROM DARK REACTIONS; 1.24. COMPLICATIONS
- 1.25. RADICAL CATION AND RADICAL ANION FORMATION1.26. A COMMENT ON THE USE OF CIRCULARLY POLARIZED LIGHT; 1.27. PHOTOCHEMISTRY FROM HIGHER EXCITED STATES; REFERENCES; Chapter 2. Experimental techniques; 2.1. WARNING; 2.2. LIGHT SOURCES; 2.3. VESSELS; 2.4. STARTING AN EXPERIMENT; 2.5. MEDIUM; 2.6. SENSITIZED REACTIONS; REFERENCES; Chapter 3. Photochemistry of the carboncarbon double bond; 3.1. INTRODUCTION; 3.2. GEOMETRIC ISOMERIZATION; 3.3. CYCLOADDITION REACTIONS; 3.4. CYCLOREVERSION REACTIONS; 3.5. ISOMERIZATION REACTIONS: DOUBLE BOND SHIFTS
- 4.4. VARIATIONS AND EMBELLISHMENTSREFERENCES; Chapter 5. Fragmentation reactions; 5.1. INTRODUCTION; 5.2. PHOTOHALOGENATION; 5.3. PHOTOLYSIS OF OTHER INORGANIC CHLORIDES; 5.4. PHOTOLYSIS OF ALKYL HALIDES; 5.5. PHOTOLYSIS OF N-HALOGENATED COMPOUNDS; 5.6. PHOTOLYSIS OF NITRITE ESTERS; 5.7. PHOTOLYSIS OF N-CHLORAMINES; 5.8. PHOTOLYSIS OF NITROAROMATIC COMPOUNDS; 5.9. PHOTOLYSIS OF AZO, DIAZO, AND AZIDE DERIVATIVES; 5 .10. OTHER FRAGMENTATION REACTIONS; REFERENCES; Chapter 6. Photochemistry with oxygen; 6.1. INTRODUCTION; 6.2. ELECTRONICALLY EXCITED FORMS OF OXYGEN; 6.3. DETECTION OF 1O2