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Multidimensional solid-state NMR and polymers /
NMR spectroscopy is the most valuable and versatile analytical tool in chemistry. While excellent monographs exist on high-resolution NMR in liquids and solids, this is the first book to address multidimensional solid-state NMR. Multidimensional techniques enable researchers to obtain detailed infor...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London ; San Diego :
Academic Press,
[1994]
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| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 100 | 1 | |a Schmidt-Rohr, K., |e author. | |
| 245 | 1 | 0 | |a Multidimensional solid-state NMR and polymers / |c K. Schmidt-Rohr and H.W. Spiess |
| 264 | 1 | |a London ; |a San Diego : |b Academic Press, |c [1994] | |
| 300 | |a 1 online resource : |b illustrations | ||
| 336 | |a text |b txt |2 rdacontent | ||
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| 588 | |a Description based on online resource; title from resource web page (viewed March 31, 2020 | ||
| 504 | |a Includes bibliographical references and index | ||
| 520 | |a NMR spectroscopy is the most valuable and versatile analytical tool in chemistry. While excellent monographs exist on high-resolution NMR in liquids and solids, this is the first book to address multidimensional solid-state NMR. Multidimensional techniques enable researchers to obtain detailed information about the structure, dynamics, orientation, and phase separation of solids, which provides the basis of a better understanding of materials properties on the molecular level. Dramatic progress-much of it pioneered by the authors-has been achieved in this area, especially in synthetic polymers. Solid-state NMR now favorably competes with well-established techniques, such as light, x-ray, or neutron scattering, electron microscopy, and dielectric and mechanical relaxation. The application of multidimensional solid-state NMR inevitably involves use of concepts from different fields of science. This book also provides the first comprehensive treatment of both the new experimental techniques and the theoretical concepts needed in more complex data analysis. The text addresses spectroscopists and polymer scientists by treating the subject on different levels; descriptive, technical, and mathematical approaches are used when appropriate. It presents an overview of new developments with numerous experimental examples and illustrations, which will appeal to readers interested in both the information content as well as the potential of solid-state NMR. The book also contains many previously unpublished details that will be appreciated by those who want to perform the experiments. The techniques described are applicable not only to the study of synthetic polymers but to numerous problems in solid-state physics, chemistry, materials science, and biophysics. Key Features * Presents original theories and new perspectives on scattering techniques * Provides a systematic treatment of the whole subject * Gives readers access to previously unpublished material * Includes extensive illustrations | ||
| 505 | 0 | |a Front Cover; Multidimensional Solid-State NMR and Polymers; Copyright Page; Table of Contents; Preface; Acknowledgements; NMR Acronyms and Abbreviations; Chapter 1. Introduction; 1.1 Overview; 1.2 Examples; 1.3 References; Chapter 2. Principles of NMR of Organic Solids; 2.1 Introduction; 2.2 Semiclassical description of pulsed NMR; 2.3 Concepts of NMR in terms of textbook quantum mechanics; 2.4 Hamiltonians and spectra; 2.5 Quantum-mechanical calculations of NMR time evolutions; 2.6 The effects of radio-frequency (rf) pulses; 2.7 References | |
| 505 | 8 | |a Chapter 3. High-Resolution NMR Techniques for Solids3.1 Introduction; 3.2 Phenomenological descriptions of pulsed techniques; 3.3 Averaging of Hamiltonians; 3.4 Further applications of average-Hamiltonian theory; 3.5 Homonuclear polarization transfer; 3.6 Time-dependent perturbation theory; 3.7 Proton-driven 13C spin diffusion, and 1H spin diffusion; 3.8 Selective excitation by hard pulses; 3.9 Magic-angle spinning (MAS); 3.10 Averaging of second-order quadrupolar couplings; 3.11 Zero-field NMR; 3.12 Multiple-quantum coherences; 3.13 Incoherent effects in solid-state NMR; 3.14 References | |
| 505 | 8 | |a Chapter 4. Fourier Theory for 1D and 2D NMR4.1 Motivation; 4.2 Basic definitions; 4.3 Useful FT relations; 4.4 Important Fourier pairs; 4.5 Specific applications of Fourier theory in NMR; 4.6 Fourier transformation in two-dimensional (2D) NMR; 4.7 Mathematical formulation of data sampling; 4.8 Consequences of data sampling; 4.9 Signal and noise; 4.10 Concluding remarks; 4.11 References; Chapter 5. Short Review of Structure and Dynamics of Solid Polymers; 5.1 Motivation; 5.2 Chain and phase structure of semicrystalline polymers; 5.3 Dynamical processes in polymers; 5.4 Solid biopolymers | |
| 505 | 8 | |a 5.5 Heterogeneous polymer systems5.6 Liquid-crystalline polymers; 5.7 List of polymer acronyms; 5.8 References; Chapter 6. Multidimensional Separation and Correlation; 6.1 Introduction; 6.2 General aspects of 2D spectra and time signals; 6.3 Separation vs. correlation -- Part I; 6.4 Separation of chemical-shift powder patterns; 6.5 Separation of MAS chemical-shift sideband patterns; 6.6 Separation of dipolar patterns by isotropic shifts; 6.7 Correlation experiments; 6.8 2D Relaxation NMR; 6.9 Separation vs. correlation -- Part II; 6.10 References | |
| 650 | 0 | |a Nuclear magnetic resonance spectroscopy. | |
| 650 | 0 | |a Polymers. | |
| 650 | 0 | |a Organic solid state chemistry. | |
| 650 | 6 | |a Spectroscopie de la r�esonance magn�etique nucl�eaire. |0 (CaQQLa)201-0072888 | |
| 650 | 6 | |a Polym�eres. |0 (CaQQLa)201-0000257 | |
| 650 | 6 | |a Chimie de l'�etat solide organique. |0 (CaQQLa)201-0278094 | |
| 650 | 7 | |a polymers. |2 aat |0 (CStmoGRI)aat300218300 | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Nuclear magnetic resonance spectroscopy. |2 fast |0 (OCoLC)fst01040333 | |
| 650 | 7 | |a Organic solid state chemistry. |2 fast |0 (OCoLC)fst01047725 | |
| 650 | 7 | |a Polymers. |2 fast |0 (OCoLC)fst01070588 | |
| 700 | 1 | |a Spiess, Hans Wolfgang, |d 1942- |e author. | |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780080925622 |z Texto completo |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780080925622 |z Texto completo |