An introduction to equilibrium thermodynamics.
An Introduction to Equilibrium Thermodynamics discusses classical thermodynamics and irreversible thermodynamics. It introduces the laws of thermodynamics and the connection between statistical concepts and observable macroscopic properties of a thermodynamic system. Chapter 1 discusses the first la...
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
New York :
Pergamon Press,
[1972]
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Colección: | Pergamon unified engineering series ;
14. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; An Introduction to Equilibrium Thermodynamics; Copyright Page; Table of Contents; Preface; Chapter 1. First Law of Thermodynamics; 1 -1 Thermodynamics; 1-2 Temperature; 1-3 Equilibrium Concepts; 1-4 Systems; 1 -5 Perfect Gas as a Thermometer; 1-6 Work; 1-7 Heat; 1-8 Heat Capacity; 1 -9 First Law of Thermodynamics; 1-10 Energy of a Perfect Gas (Translational Degrees of Freedom); 1-11 Thermodynamic Properties; 1-12 Specific Heat at Constant Volume ; 1-13 Specific Heat at Constant Pressure; 1-14 Reversible Process; 1-15 Carnot Cycle; 1-16 Non-mechanical Work; Problems; References.
- Chapter 2. The Statistical Inference of Thermodynamics2-1 Systems and Ensembles; 2-2 Probability; 2-3 Uncertainty of the Statistics; 2-4 Entropy and Equilibrium; 2-5 The Probability Distribution; 2-6 Alternate Method of Formulating the Probability Distribution; 2-7 The Partition Function; 2-8 The Third Law of Thermodynamics; 2-9 Grand Partition Function; Problems; References; Chapter 3. Ideal Gas System: Maxwell-Boltzmann, Fermi-Dirac, Bose-Einstein; 3-1 Schr�odinger Wave Equation; 3-2 Wave Equation for Ideal Monatomic Gas; 3-3 Subsystems; 3-4 Degeneracy; 3-5 The Ideal Monatomic Gas.
- 3-6 Maxwell-Boltzmann Distributions3-7 Fermi-Dirac and Bose-Einstein Gases; 3-8 The Ideal MB Gas as the Limit of F D and BE Statistics; 3-9 Black Body Radiation (An Example of a Photon Gas); 3-10 Electron Gas in Metals (Perfect Electron Gas); Problems; References; Chapter 4. Ideal Diatomic Gas and Perfect Crystal; 4-1 Model of Ideal Diatomic Gas; 4-2 Translational Partition Function; 4-3 Rotational Partition Function; 4-4 Vibrational Partition Function
- Harmonic Oscillator; 4-5 Electronic Partition Function; 4-6 Summary of Diatomic Gas; 4-7 Perfect Crystal; Problems; References.
- Chapter 5. Second Law of Thermodynamics5-1 A Macroscopic Look at Entropy; 5-2 Second Law of Thermodynamics; 5-3 Entropy in a Reversible System; 5-4 Entropy in an Irreversible System; 5-5 Clausius' Inequality; Problems; References; Chapter 6. Thermodynamic Functions; 6-1 Transformation of Thermodynamic Variables; 6-2 Legendre Transformation; 6-3 Enthalpy; 6-4 Helmholtz Function; 6-5 Gibbs Function; 6-6 Relationship Between Helmholtz and Massieu Functions; 6-7 Legendre Transformation of Entropic Form of the Fundamental Equation; 6-8 Maxwell Relations; 6-9 Example Proble-Osmosis.
- 6-10 Extensive and Intensive Thermodynamic State Parameters6-11 Jacobian Transformations; 6-12 Integration of dU; Problems; References; Chapter 7. Flow Systems; 7-1 Steady State System; 7-2 Pure Substances; 7-3 Tabulated Properties; 7-4 Some Specific Flow Processes; 7-5 General Flow Process; Problems; References; Chapter 8. Thermal Energy Converters; 8-1 Closed and Open System Analysis; 8-2 Closed System Analysis; 8-3 Rankine Cycle; Problems; References; Chapter 9. Non-reactive Mixtures of Ideal Gases; 9-1 Mass Fractions and Mole Fractions; 9-2 Gibbs-Dalton Law; 9-3 Partial Volume Concepts.