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Fundamentals of electrochemical science /
"[Fundamentals of Electrochemical Science] is a valuable contribution and I support the publication ... I am looking forward to seeing this book on the shelves, and once published, I will not hesitate to recommend itto my students."--ANDRZEJ WIECKOWSKI, University of Illinois at Urbana-Cha...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
San Diego :
Academic Press,
�1994.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Fundamentals of Electrochemical Science; Copyright Page; Table of Contents; Preface; Glossary of Symbols and Abbreviations; Italic letters; Roman letters; Greek letters; Subscripts; Superscripts; Functions, operators, etc; Chapter 1. The Conduction of Electricity; 1:1 Electric charge and electric current; 1:2 Electrical potential and electric field; 1:3 Ohm's law; 1:4 Classes of conductors; 1:5 Mobilities; 1:6 Contact potential differences; 1:7 Capacitance; 1:8 Laplace transformation; 1:9 Summary; Problems; Chapter 2. Ionic Solutions; 2:1 Electroneutrality; 2:2 Ionic strength
- 2:3 Activities2:4 Solutions of extremely low ionic strength; 2:5 Solutions of moderate ionic strength; 2:6 Solutions of high ionic strength; 2:7 Equilibria in ionic solutions; 2:8 Electrochemical activities; 2:9 Transfer equilibria; 2:10 Adsorption; 2:11 Summary; Problems; Chapter 3. Electrochemical Cells; 3:1 Cell voltages and currents; 3:2 Thermodynamics of equilibrium cells; 3:3 Cells with junctions; 3:4 Utility of equilibrium cells; 3:5 Electrochemical power sources; 3:6 Electrosynthesis; 3:7 Electrochemistry in the metals industry; 3:8 Corrosion cells; 3:9 Summary; Problems
- Chapter 4. Electrodes4:1 Electrode potentials; 4:2 Reference electrodes; 4:3 Standard electrode potentials; 4:4 Versions of the Nernst equation; 4:5 Pourbaix diagrams; 4:6 Working electrodes; 4:7 Mercury as a working electrode; 4:8 Ion-selective electrodes; 4:9 Summary; Problems; Chapter 5. Electrode Reactions; 5:1 Electrochemical equations; 5:2 Types of electrode reaction; 5:3 Faraday's laws; 5:4 Feasibility of electrode reactions; 5:5 The totally polarized electrode; 5:6 Electrode reaction mechanisms; 5:7 Kinetics of electron transfer; 5:8 The Butler-Volmer equation
- 5:9 Kinetics of complex electrode reactions5:10 Summary; Problems; Chapter 6. Polarization; 6:1 Sign conventions; 6:2 Non-equilibrium cell voltages; 6:3 Ohmic polarization; 6:4 Activation polarization; 6:5 Mixed potentials; 6:6 Concentration polarization; 6:7 Changes with time; 6:8 Absence of product; 6:9 The third electrode; 6:10 Summary; Problems; Chapter 7. Transport; 7:1 Flux density; 7:2 Transport mechanisms; 7:3 Laws of migration; 7:4 Electrophoresis; 7:5 Laws of diffusion; 7:6 Partial solution of Fick's laws; 7:7 The Nernst-Einstein law; 7:8 Transport by diffusion plus migration
- 7:9 Laws of convection7:10 Transport to a rotating disk; 7:11 Transport to the dropping mercury electrode; 7:12 Flux densities at an electrode; 7:13 Summary; Problems; Chapter 8. Steady-State Voltammetry; 8:1 Voltammetry in general; 8:2 The steady state; 8:3 Thin-layer cells; 8:4 Membrane permeation cells; 8:5 Microelectrodes; 8:6 Limiting currents; 8:7 Reversibility; 8:8 Voltammetry at a rotating disk electrode; 8:9 Steady-state multi-step reactions; 8:10 Summary; Problems; Chapter 9. The Electrode Interface; 9:1 The electrical double layer; 9:2 The Gouy-Chapman model