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Advances in physical organic chemistry. Volume 44 /
Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics. * Revie...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford, UK ; Burlington, MA :
Academic Press,
�2010.
|
| Edición: | 1st ed. |
| Colección: | Advances in physical organic chemistry,
v. 44 |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
MARC
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| 072 | 7 | |a SCI |x 013040 |2 bisacsh | |
| 082 | 0 | 4 | |a 547.1 |2 22 |
| 245 | 0 | 0 | |a Advances in physical organic chemistry. |n Volume 44 / |c editor, John P. Richard. |
| 250 | |a 1st ed. | ||
| 260 | |a Oxford, UK ; |a Burlington, MA : |b Academic Press, |c �2010. | ||
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 490 | 0 | |a Advances in physical organic chemistry, |x 0065-3160 ; |v v. 44 | |
| 504 | |a Includes bibliographical references and indexes. | ||
| 588 | 0 | |a Print version record. | |
| 520 | |a Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics. * Reviews the application of quantitative and mathematical methods towards understanding chemical problems * Multidisciplinary volumes cover organic, organometallic, bioorganic, enzymes and materials topics. | ||
| 505 | 0 | |a Cover; ADVISORY BOARD; Advances inPhysical Organic Chemistry; Copyright Page; Contents; Editor's Preface; Contributors to Volume 44; Biographical Essay: A. Jerry Kresge; 1 Introduction; 2 Solvent deuterium isotope effects; 3 Br�nsted coefficients; 4 Generation of reactive intermediates by laser flashphotolysis; Acknowledgments; References; Chapter 1 The low-barrier hydrogen bond in enzymic catalysis; 1 Introduction; 2 Properties of hydrogen bonds; 3 Role of low-barrier hydrogen bonds in enzymatic reactions; 4 Conclusion; References; Chapter 2 Stabilities and Reactivities of Carbocations | |
| 505 | 8 | |a 1 Introduction2 Stabilities of carbocations; 3 Reactivity of carbocations; Acknowledgments; References; Chapter 3 Secondary equilibrium isotope effects on acidity; 1 Scope; 2 Theory; 3 Methodology; 4 Secondary deuterium isotope effects on acidities in solution; 5 Heavy-atom isotope effects on acidities; 6 Secondary isotope effects on Lewis acid-Lewis base interactions; 7 Secondary isotope effects on gas-phase acidity and basicity; 8 Secondary isotope effects on conformational equilibrium; 9 Secondary isotope effects on tautomeric equilibria; 10 Secondary isotope effects on hydrogen bonding | |
| 505 | 8 | |a 11 Secondary isotope effects in chromatography12 Secondary isotope effects on molecular structure; 13 Origin of secondary isotope effects on acidity; Acknowledgments; References; Chapter 4 Molecular dynamics simulations and mechanism of organic reactions: non-TST behaviors; 1 Introduction; 2 Nonstatistical product distribution; 3 Avoided intermediate on IRC; 4 Non-IRC reaction pathway; 5 Path bifurcation; 6 Reaction time course and product and energy distributions; 7 Nonstatistical barrier recrossing; 8 QM/MM-MD; 9 Full quantum MD simulation in water; 10 Summary and outlook; Acknowledgments | |
| 505 | 8 | |a 1 Catalysis and reversibility2 Catalysis of decarboxylation; 3 Decarboxylation, internal return, and directionality; 4 Pre-association; 5 Catalyzing thiamin diphosphate catalysis; 6 12C/13C kinetic isotope effects and pre-association catalysis; 7 Implications of blocking reversion for enzyme catalysis; 8 OMP decarboxylase -- decarboxylation and protonation of orotidine monophosphate; 9 General trends in catalyzed decarboxylation; 10 Decarboxylation of aromatic carboxylic acids; 11 Decarboxylation of 3-ketoacids; 12 Conclusions; References; AUTHOR INDEX; Cumulative Index of Authors | |
| 650 | 0 | |a Physical organic chemistry. | |
| 650 | 6 | |a Chimie organique physique. |0 (CaQQLa)201-0034746 | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Physical organic chemistry |2 fast |0 (OCoLC)fst01715687 | |
| 700 | 1 | |a Richard, J. P. |q (John P.) | |
| 776 | 0 | 8 | |i Print version: |t Advances in physical organic chemistry. Volume 44. |d Oxford, UK ; Burlington, MA : Academic Press, �2010 |z 9780123815248 |w (OCoLC)473442284 |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780123815248 |z Texto completo |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/bookseries/00653160/44 |z Texto completo |