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Structure and dynamics of solutions /
Recent advances in the study of structural and dynamic properties of solutions have provided a molecular picture of solute-solvent interactions. Although the study of thermodynamic as well as electronic properties of solutions have played a role in the development of research on the rate and mechani...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; New York :
Elsevier,
1992.
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| Colección: | Studies in physical and theoretical chemistry ;
79. |
| Temas: | |
| Acceso en línea: | Texto completo Texto completo |
Tabla de Contenidos:
- Front Cover; Structure and Dynamics of Solutions; Copyright Page; Preface; List of Contributors; Table of Contents; Chapter 1. Introduction; Chapter 2. Structure of Solutions by Diffraction, EXAFS, and XANES Methods; 2.1 Apparatus Used for X-Ray and Neutron Diffraction and for EXAFS and XANES Measurements; 2.2 Structure of Liquids and Solutions by X-Ray and Neutron Diffraction; 2.3 Structure of Solvated Ions and Metal Complexes in Solution Studied by the Diffraction Method; 2.4 Structure of Metal Complexes in Solution by the EXAFS and XANES Methods; References
- Chapter 3. Molecular Dynamics Simulations of Liquids and Solutions3.1 Computer Experiments; 3.2 Local Composition in Lennard-Jones Mixtures; 3.3 Computer Simulations of Fluid Water and Its Liquid-Gas Interface with Carravetta-Clementi Potential; 3.4 Hydration in Dilute Aqueous Solution of Nonelectrolytes; 3.5 The Structure of Hydrated Ions in Aqueous Solutions as Studied by the Molecular Dynamics Simulations; 3.6 Molecular Dynamics Studies on Electric Conductivity of Ionic; REFERENCES; Chapter 4. Dynamic Properties of Liquids and Solutions; 4.1 Dynamic Properties of Ions in Solutions
- 4.2 Dynamics of Ions and Solvent Molecules in Solution -Nuclear Magnetic Relaxation Studies4.3 Association of Alkylammonium Salts in Nonaqueous Solvents; 4.4 Water and Metal Ions at Water-Amphiphile Interfaces; REFERENCES; Chapter 5. Effects of Pressure and Temperature; 5.1 Pressure and Temperature Effects on Irreversible Processes in Solution; 5.2 Some New Apparatus; 5.3 Molecular Conformation in Solution; REFERENCES; Chapter 6. Ion-Ion and Ion-Solvent Interactions and Complex Formation in Solution; 6.1 Solvent Properties and Reactions in Solution
- 6.2 Solute-Solvent Interactions of Metal Chelate Electrolytes6.3 Reaction and Activation Volumes for Some Reactions Involving Metal Complexes in Solution; 6.4 Ion-Triplets as the Precursor for Electron Transfer Reactions of Coordination Compounds; 6.5 Mechanism of Sulfur-Inversion in Platinum(II)-Thioether Complexes Revisited; REFERENCES; Chapter 7. Energetic Aspects on Solute-Solvent Interactions; 7.1 Thermodynamic Aspects of Complex Formation Reactions in Nonaqueous Solutions; 7.2 Statistical Mechanical Approaches to the Structure and Thermodynamic Properties of Solutions
- 7.3 Electronic States of Ions and Molecules in Solution Studied by Photoelectron Emission SpectroscopyREFERENCES; Concluding Remarks; Subject Index