Chemistry at interfaces /

For scientists and students in material chemistry (coatings, corrosion, and so on), physical chemistry (catalysis, analysis), biophysics, bioengineering, and microelectronics. A practical approach to setting up and using interfacial techniques and to interpreting measurements. Emphasis is on experi.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: MacRitchie, Finlay
Formato: Electrónico eBook
Idioma:Inglés
Publicado: San Diego : Academic Press, �1990.
Temas:
Surface chemistry.
Chimie des surfaces.
SCIENCE > Chemistry > Physical & Theoretical.
Surface chemistry
Oberfl�achenchemie
Surfaces > Chemical properties
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover
  • Chemistry at Interfaces
  • Copyright Page
  • Table of Contents
  • Preface
  • Chapter 1. Introduction
  • Chapter 2. Theoretical Concepts I
  • I. What Makes a Reaction Go?
  • II. Quantitative Measurements of Free Energy
  • III. Application of Thermodynamic Principles to Interfacial Phenomena
  • IV. The Hydrophobic Effect
  • Demonstrations
  • Problems
  • References
  • Chapter 3. Theoretical Concepts II
  • I. The Distribution of Molecules
  • II. Quantum Energy Levels and Partition Functions
  • III. Principle of Independent Surface Action
  • IV. Important Intensive Properties for InterfacesV. Distribution of Molecules between Bulk and Interface
  • VI. Effects of an Interface on the Orientation of Molecules
  • VII. Reaction Rates at Interfaces
  • Demonstrations
  • Problems
  • References
  • Chapter 4. The Film Balance and the Measurement of Interfacial Pressure
  • I. The Problem of Purity in Interfacial Work
  • II. The Film Balance
  • III. Modifications to Basic Film Balance
  • IV. Spreading of Monolayers
  • Demonstrations
  • Problem
  • References
  • Chapter 5. Additional Techniques I
  • I. Interfacial PotentialII. Interfacial Rheology
  • III. Transfer of Films to Solid Supports
  • IV. Radioactive Tracers
  • Demonstrations
  • Problems
  • References
  • Chapter 6. Additional Techniques II
  • I. Optical Techniques
  • II. Solid/Fluid Interfaces
  • III. Forces between Surfaces
  • Demonstrations
  • Problem
  • References
  • Chapter 7. Monolayers
  • I. Monolayer States
  • II. The Clausius-Clapeyron Equation
  • III. Equilibrium Spreading Pressure
  • IV. Effects of Systematic Change of Molecular Structure on Monolayer Properties
  • v. Monolayers at the Oil/Water InterfaceVI. Monolayers of More Complex Molecules
  • Demonstration
  • Problems
  • References
  • Chapter 8. Physical Processes at Interfaces
  • I. Adsorption
  • II. Desorption
  • III. Spreading or Two-Dimensional Dissolution
  • IV. Precipitation of Monolayers
  • V. Molecular Configurational Changes
  • VI. Surface Flow
  • VII. Transport across Interfaces
  • VIII. Unidimensional Interfaces
  • IX. General Summary
  • Demonstrations
  • Problems
  • References
  • Chapter 9. Chemical Reactions
  • I. Kinetics of Reactions Studied by the Film BalanceII. Specific Reactions Studied in Monolayers
  • III. Polymerization Reactions
  • IV. General Features of Interfacial Reactions
  • V. Design of Functionalized Monolayer Systems
  • VI. Unidimensional and Zero-Dimensional Reactions
  • Demonstrations
  • Problem
  • References
  • Chapter 10. Biological Processes and Reactions
  • I. Membrane-Mimetic Chemistry
  • II. Enzyme Reactions at Interfaces
  • III. Direct Studies on Model Membrane Systems
  • IV. The Pulmonary Surfactant
  • V. Thrombogenicity

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