Advances in organometallic chemistry. Volume 49 /

Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enorm...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: West, Robert, 1928-, Hill, Anthony F.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam : Academic Press, 2003.
Colección:Advances in organometallic chemistry ; v. 49.
Temas:
Organometallic compounds.
Organometallic chemistry > Research.
Organometallic Compounds
Compos�es organom�etalliques.
Chimie organom�etallique > Recherche.
organometallic compound.
Organometallic compounds
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Advances in Organometallic Chemistry; Copyright Page; Contents; Contributors; Chapter 1. Decamethylsilicocene: Synthesis, Structure, Bonding and Chemistry; I. Introduction; II. Synthesis and Structure of Decamethylsilicocene; III. Bonding in Decamethylsilicocene; IV. Chemistry of Decamethylsilicocene (1); V. Conclusions and Perspectives; References; Chapter 2. Organometallic Phosphorous and Arsenic Betaines; I. Introduction; II. Synthesis of Betaines (+)E15-C-E14-X(
  • ) (I) and (+)E15-C-E14(
  • ) (II) (E15 = P, As; E14 = Si, Ge, Sn; X = C, S)
  • III. Structure of Betaines (+)E15-C-E14-X(
  • ) I and (+)E15-C-E14(
  • ) II According to X-ray DataIV. NMR Parameters of Betaines (+)E15-C-E14-X(
  • ) I and (+)P-C-E14(
  • ) II; V. Reactivity of Betaines (+)E15-C-E14-X(
  • ) I and (+)E15-C-E14(
  • ) II (E15 = P, As; E14 Si, Ge, Sn; X = S); VI. Quantum-Chemical Investigation of Potential Energy Surfaces of Betaines (+)E15-C-E14-X(
  • ) I and (+)E15-C-E14(
  • ) II; VII. Conclusion; References; Chapter 3. Coordination Compounds with Organoantimony and Sbn Ligands; I. Introduction; II. Complexes with R3Sb, R2SbX, AND RSbX2 (R = alkyl, aryl, SiMe3
  • X = halogen, OR, SR) LigandsIII. Complexes with R2Sb-SbR2 AND R2Sb (R = alkyl, aryl) Ligands; IV. Complexes with R2Sb-Y-SbR2 (R = alkyl, aryl; Y = CH2, O, S) Ligands; V. Complexes with R2Sb-Yn-SbR2 (R = alkyl, aryl; Yn = (SbR)2, 0-C6H4, (CH2)3, S(MeSb)S) Ligands; VI. Complexes with (RSb)n (R = alkyl, aryl) and Sbn Ligands; VII. Concluding Remarks; References; Chapter 4. Ladder Polysilanes; I. Introduction; II. Synthesis; III. Structure; IV. Electronic Properties; V. Reactions; VI. Conclusion; References
  • Chapter 5. Structure-Reactivity Relationships in the Cyclo-Oligomerization of 1,3-Butadiene Catalyzed by Zerovalent Nickel ComplexesI. Introduction; II. Catalytic Reaction Cycles for the Nickel-Catalyzed Cyclo-Oligomerization of 1,3-Butadiene; III. Computational Models and Methods; IV. Theoretical Exploration of Critical Elementary Reaction Steps; V. Influence of Electronic and Steric Factors on Individual Elementary Steps of the C8-Cyclo-Oligomer Generating Reaction Channel; VI. Theoretically Re.ned Catalytic Cycles for the Nickel-Catalyzed Cyclo-Oligomerization Reactions of 1,3-Butadiene
  • VII. Regulation of the Cyclo-Oligomer Product SelectivityVIII. Regulation of the C8:C12-Cyclo-Oligomer Product Distribution; IX. Conclusion; References; Chapter 6. Group 13/15 Organometallic Compounds-Synthesis, Structure, Reactivity and Potential Applications; I. Introduction; II. Lewis Acid-Base Adducts; III. Compounds of the Type [R2MER'2]x; IV. Monomers, Heterocycles and Cages of the Type [RMER']x; V. Potential Applications of Group 13/15 Organoelement Compounds in Material Sciences; VI. Conclusions and Outlook; References; Index; Cumulative List of Contributors for Volumes 1-36

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