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Advances in inorganic chemistry. Volume 55 /
Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable r...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam :
Academic Press,
2004.
|
| Colección: | Advances in inorganic chemistry ;
v. 55. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Advances in Inorganic Chemistry; Copyright Page; Contents; Preface; Chapter 1. Dioxygen Activation by Transition Metal Complexes. Atom Transfer and Free Radical Chemistry in Aqueous Media; I. Introduction; II. Preparation and Characterization; III. Reactivity; IV. Conclusions and Future Directions; V. Abbreviations; References; Chapter 2. Redox Reactivity of Coordinated Ligands in Pentacyano(L)Ferrate Complexes; I. Introduction; II. General Properties of the Nitroprusside ion, [Fe(CN)5NO]2- (NP), and Related Nitrosyl Complexes
- III. The Coordination Chemistry of NO. Formation and Dissociation ReactionsIV. The Redox Reactivity of Bound NO; V. The Electrophilic Reactions of Bound NO; VI. The Autooxidation of Hydrazine; VII. The Oxidation of Amines and Alcohols; VIII. The Disproportionation of Hydroxylamine; IX. Miscellaneous Reactions; X. Conclusions; References; Chapter 3. Carbonato Complexes: Models for Carbonic Anhydrase; I. Introduction; II. Carbonic Acid, Bicarbonate, and Carbonate; III. The Chemistry of Metal Carbonates; IV. Kinetics and Mechanism of Formation and Aquation/Decarboxylation Reactions
- IV. FerrocenesV. Osmium and Ruthenium Compounds; VI. Chiral Complexes; VII. Cyclometalated Ruthenium(II) and Osmium(II)Mediators; VIII. Concluding Remarks; References; Chapter 5. Properties of Transition Metal Complexes with Metal-Carbon Bonds in Aqueous Solutions as Studied by Pulse Radiolysis; I. Introduction; II. Radiolysis of Aqueous Solutions; III. Reaction of Aliphatic Carbon-Centered Radicals with TransitionMetal Complexes in Aqueous Solutions; IV. Formation of Transition Metal Complexes with Metal-Carbon s-Bonds; V. Properties of Complexes with Metal-Carbon s-Bonds
- VI. Mechanisms of Decomposition of the Transient Complexes LmMn+1-RVII. Alkene Complexes; VIII. Complexes with Metal-Carbon s-Bonds Formed in Redox Processes Between Transition Metal Complexes and Organic Substrates; IX. Elucidation of the Mechanisms of Catalytic Processes; References; Chapter 6. Transition Metal Complexes with Bis(Hydrazone) Ligands of 2,6-Diacetylpyridine. Hepta-Coordination of 3d Metals; I. Introduction; II. Aspects Studied; III. Concluding Discussion; References; Chapter 7. Potential Applications for the Use of Lanthanide Complexes as Luminescent Biolabels; I. Scope