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Advances in physical organic chemistry. Volume 32 /
Volume 32 is proof again of the platform provided by Advances in Physical Organic Chemistry for some of the most interesting and diverse papers being produced today. Contributions by academic and industrial chemists give the volume a perspective useful to those working in both fields.
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London ; New York :
Academic Press,
1999.
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| Colección: | Advances in physical organic chemistry ;
32 |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Advances in Physical Organic Chemistry, Volume 32; Copyright Page; Contents; Preface; Contributors to Volume 32; Chapter 1. Perspectives in Modern Voltammetry: Basic Concepts and Mechanistic Analysis; 1. Introduction; 2. General concepts of voltammetry; 3. Cyclic voltammetry; 4. Hydrodynamic voltammetry; 5. Microelectrodes; 6. Sonovoltammetry; 7. Theoretical modelling; 8. A comparison of voltammetric techniques; 9. Current and future direction of voltammetry; Appendix; References; Chapter 2. Organic Materials for Second-Order Non-Linear Optics; 1. Introduction
- 2. Basics of non-linear optics3. Quantum-chemical basis for second-order polarizabilities; 4. Non-linear optical susceptibilities and experimental methods to evaluate x(2) and �; 5. Optimization of second-order polarizabilities: applications to real molecules; 6. Conclusion; Acknowledgements; References; Chapter 3. Tautomerism in the Solid State; 1. Introduction; 2. Proton tautomerism in an isolated system; 3. Proton tautomerism in the solid state; 4. Photochromism and thermochromism derived from proton tautomerism; 5. Photochemical hole-burning
- 6. Dielectric properties derived from proton tautomerism in crystals7. Concluding remarks; Acknowledgements; References; Chapter 4. The Yukawa-Tsuno Relationship in Carbocationic Systems; 1. Introduction; 2. Applications of the Yukawa-Tsuno equation; 3. Yukawa-Tsuno correlations for benzylic sololyses generating carbocations; 4. Carbocation formation equilibria; 5. Yukawa-Tsuno correlations for electrophilic addition of; 6. Structure-reactivity relationship in polyarylcarbocation systems; 7. Stabilities of carbocations in the gas phase; 8. Theoretically optimized structures of carbocations
- 9. Reaction mechanisms and transition-state shifts10. Concluding remarks; Acknowledgements; References; Author Index; Cumulative Index of Authors; Cumulative Index of Titles