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Advances in physical organic chemistry. Vol. 41 /
Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics. * Revie...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam :
Academic Press,
2006.
|
| Colección: | Advances in physical organic chemistry,
v. 41 |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Contents; Editor's Preface; Volume 41-Advances in Physical Organic Chemistry; Contributors to Volume 41; The interpretation and mechanistic significance of activation volumes for organometallic reactions; Introduction: basic principles and theory; Experimental; Volumes of activation for thermal organometallic reactions; Volumes of activation for radiation-induced organometallic reactions; Concluding remarks; Acknowledgements; References; Kinetic and mechanistic studies of the reactivity of Zn-OHn (n = 1 or 2) species in small molecule analogs of zinc-containing metalloenzymes
- Pyranosyl oxocarbenium ion conformations and reactivityComputational analyses of oxocarbenium ion reactions; Mechanistic studies of ''synthetic'' reactions and glycon donors; Experimental gas-phase studies; Conclusions; Acknowledgments; References; Effect of enzyme dynamics on catalytic activity; Introduction; Proton transfer and rate-promoting vibrations; Examples of rate-promoting motions in enzymatic systems; Description in atomic detail of correlated protein motions; Conformational fluctuations; References; Cumulative Index of Authors; Cumulative Index of Titles; Subject Index