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Applications of nuclear magnetic resonance spectroscopy in organic chemistry /
Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition covers the theoretical background necessary for the intelligent application of NMR spectroscopy to common problems encountered in organic chemistry. This book is composed of five parts, and begins with introd...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford ; New York :
Pergamon Press,
[1969]
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| Edición: | 2d ed. |
| Colección: | International series of monographs on organic chemistry ;
v. 10. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry; Copyright Page; Dedication; Table of Contents; Preface; Preface to the 1st Edition; Editorial Preface to the 2nd Edition; PART 1: An introduction to the theory and practice of nuclear magnetic resonance spectroscopy; Chapter 1-1. THEORY OF NUCLEAR MAGNETIC RESONANCE; A. Dynamic and magnetic properties of atomic nuclei; B. Nuclear resonance; C. Relaxation processes; D. Chemical effects in n.m.r.; Chapter 1-2. THE EXPERIMENTAL METHOD; A. The nuclear magnetic resonance spectrometer.
- B. Experimental factors which influence resolution and the shapes of absorption linesC. Experimental factors which influence sensitivity (signal-to-noise ratio); D. Measurement of line positions and determination of the chemical shift; E. Measurement of intensities; F. Solvents; G. Deuterium exchange; PART 2: Theory of chemical effects in nuclear magnetic resonance spectroscopy; Chapter 2-1. TIME-DEPENDENT EFFECTS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; Chapter 2-2. THEORY OF THE CHEMICAL SHIFT; A. Classification of shielding effects; B. Local diamagnetic proton shielding.
- C. Long range shieldingD. Contact shifts; E. The hydrogen bond; F. Solvent effects; Chapter 2-3. THEORY OF SPIN-SPIN MULTIPLICITY; A. Recognition of spin-spin multiplets; B. The mechanism of spin-spin coupling; C. Analysis of n.m.r. spectra; Chapter 2-4. THEORY AND APPLICATIONS OF MULTIPLE IRRADIATION; A. Theory; B. Applications; PART 3: Applications of the chemical shift; Chapter 3-1. GENERAL CONSIDERATIONS; Chapter 3-2. PROTONS BONDED TO NON-CYCLIC Sp3 CARBON ATOMS; Chapter 3-3. PROTONS BONDED TO NON-AROMATIC Sp2 CARBON ATOMS; A. Olefinic protons H-C=C; B. Formyl protons H-C=X.
- Chapter 3-4. PROTONS BONDED TO sp CARBON ATOMSChapter 3-5. PROTONS BONDED TO sp3 CARBON ATOMS IN NON-AROMATIC CYCLIC STRUCTURES; Chapter 3-6. PROTONS BONDED TO AROMATIC AND HETEROCYCLIC CARBON ATOMS; A. Benzene derivatives; B. Polynuclear and non-benzenoid carbocyclic aromatic compounds; C. Heterocyclic compounds; Chapter 3-7. PROTONS BONDED TO ELEMENTS OTHER THAN CARBON; A.-OH, -NH and -SH groups; Chapter 3-8. STEREOCHEMISTRY AND THE CHEMICAL SHIFT; A. Symmetry arguments; B. Geometrical isomerism in ethylene derivatives; C. Geometrical isomerism in systems containing C=N and N= N bonds.
- D. Cyclopropanes and heterocyclopropanesE. Multi-ring structures; F. Cis-trans stereochemistry in four-, five-, and six-membered rings; G. The chemical shifts of axial and equatorial protons and groups attached to six-membered rings in chair conformation; H. Chemical shift-stereochemistry correlations in some complex natural products; I. Conformation; J. Stereochemistry and the solvent shift ; Chapter 3-9. CARBONIUM IONS, CARBANIONS AND RELATED SYSTEMS; A. Carbonium ions; B. Carbanions; PART 4: Spin-spin coupling; Chapter 4-1. GEMINAL INTERPROTON COUPLING.