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Advances in organometallic chemistry Volume 16, Molecular rearrangements /
ADVANCES ORGANOMETALLIC CHEMISTRY V16.
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York ; London :
Academic Press,
1977.
|
| Colección: | Advances in organometallic chemistry ;
v. 16. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Molecular Rearrangements; Copyright Page; Contents; List of Contributors; Preface; Introduction; Chapter 1. 1,2-Anionic Rearrangements of Organosilicon and Germanium Compounds; I. Introduction; II. The Hydrazine (N?N) Rearrangement; III. The Hydroxylamine (O?N) Rearrangement; IV. The Wittig (0?C) Rearrangement; V. The S?C Rearrangement; VI. The N?C Rearrangement; VII. Other Anionic Rearrangements, Known and Unknown; References; Chapter 2. Dyotropic Rearrangements and Related s-s Exchange Processes; I. Introduction; II. Thermal Rearrangement of 1,2-Bis(Silyl) Derivatives
- III. Thermal Rearrangement of Allyl Silylmethyl EthersIV. Thermal Rearrangement of Benzyl Silylmethyl Ethers: A Case for Anchimerically Accelerated Unimolecular Bond Homolysis; V. Thermal Rearrangement of N,N-Bis(Trimethylsilyl)-0-Allylhydroxylami~; VI. Thermal Rearrangement of Bis- and Tris(Silyl)hydroxylamines; VII. Thermal Rearrangement of Squaric Acid Bis(Trimethylsilyl) Ester .; VIII. Miscellaneous s-s Exchange Reactions; IX . Outlook; References; Chapter 3. Rearrangements of Unsaturated Organoboron and Organoaluminum Compounds; I. Introduction
- II. Sigmatropic Rearrangements of OrganoboranesIII. Migrations in Tetracoordinate Organoboranes; IV. Allylic Isomerizing or Derivatizing Reactions of Organoalanes; V. Carbalumination via Intermediate Complexes; VI. Prospects for Future Developments; References; Chapter 4. Rearrangements of Organoaluminum Compounds and Their Group III Analogs; I. Introduction; II. Structures and Bonding in Group III Derivatives; III. Monomer-Dimer Equilibria; IV. Exchange Processes Involving Dissociated Species; V. Exchange Reactions of Group III Alkyl Addition Compounds; VI. Intramolecular Exchange Processes
- VII. Intermolecular Exchange Involving Partial DissociationVIII. Processes Involving Metal-Multiple Bond Interactions; References; Chapter 5. Organomagnesium Rearrangements; I. lntroduction; II. Intramolecular Addition and Ring-Cleavage Rearrangements; III. Rearrangement of Allylic Organomagnesium Compounds; IV.1,2-Shifts; References; Chapter 6. Aryl Migrations in Organometallic Compounds of the Alkali Metals; I. Introduction; II. Migrations of Aryl Groups in Anions; III. Migrations of Aryl in Intermediate Radicals
- IV. Migrations of Aryl in Radical Anions of Aromatic Hydrocarbons and Related ReactionsV. Migration of Phenyl in Competition with Cleavage of Benzyl; VI. Conclusions; References; Chapter 7. Fluxional and Nonrigid Behavior of Transition Metal Organometallicp-Complexes; I. Introduction; II. Developments in Instrumentation and Technique; III. Ring Whizzers; IV. Rotation of p-Complexes; V. Coupling of p-Ligand Rotation with Carbonyl Rearrangement; References; Chapter 8. s-p Rearrangements of Organotransition Metal Compounds; I. Scope and Limitation; II. Factors Influencing the Static Modes