Cargando…
Advances in organometallic chemistry. Volume 36 /
This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry-the study of compounds contai...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
San Diego :
Academic Press,
1994.
|
| Colección: | Advances in organometallic chemistry ;
v. 36. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Advances in Oraganometallic Chemistry, Volume 36; Copyright Page; Contents; Contributors; Chapter 1. Early Carboranes and Their Structural Legacy; I. Background and Introduction; II. Carboranes, Carbocations, and Polyboranes; III. Skeletal Electron Pair Bonds Identified by styx and Chop-Stx; IV. Classification Based on Geometry, Empirical Formula, and Electron Pair Bond Relationships; V. Polyborane Lewis Base Adducts; VI. Electron Counting; VII. Carborane Nomenclature; VIII. nido-Carboranes and Related Compounds; IX. arachno-Carboranes and Related Compounds
- X. hypho-Carboranes and Related CompoundsXI. Conclusion; References; Chapter 2. Organometallic Derivatives of Fullerenes; I. Introduction; II. Endohedral Complexes; III. Fullerenes with Metal-Containing External Substituents; IV. Interstitial Substitution and Salt Formation; V. Substitution for Framework Carbon; VI. Conclusions; References; Chapter 3. Quantification of Steric Effects in Organometallic Chemistry; I. Introduction; II. Quantification of Steric Size Using Physical Measurements; III. Quantification of Steric Size Using Molecular Mechanics Methods
- IV. Quantification of Steric Size Using Chemical MethodsV. Quantification of the Variation in Steric Effect with Distance; VI. Steric Profiles and Thresholds; VII. Quantification of Steric Size Using Molecular Volumes; VIII. Some Applications of Steric Size Measurements; IX. Conclusion; References; Chapter 4. Organotransition Metallic Chemistry of Sulfur Dioxide Analogs; I. Introduction and Scope; II. General Coordination Chemistry; III. Triatomic Interchalcogens; IV. Sulfines (Alkylideneoxo-?4-sulfuranes, Thione-S-oxides); V. N-Sulfinylamines (Iminooxo-?4-sulfuranes)
- VI. Sulfur Diimides (Diimino-?4-sulfuranes)VII. Thiazate and Related Ligands; VIII. Concluding Remarks; References; Chapter 5. Silaorganometallic Chemistry on the Basis of Multiple Bonding; I. Introduction; II. Silylene Complexes; III. Silane-Induced CO-Activation Reaction; IV. Cyclic Silylene Complexes; V. Donor-Stabilized Silylyne Complexes; VI. Silaethene Complexes; VII. Silaimine Complexes; VIII. Disilaethene Complexes; IX. Silatrimethylenemethane Complexes; X. Metallasilaallenes; XI. Prospects; References; Chapter 6. Organometallic Chemistry of the Lanthanides; I. Introduction
- II. Homoleptic Alkyl ComplexesIII. Alkoxides; IV. Thiolates; V. Selenides and Tellurolates; VI. Nitrogen Donor Ligands; VII. p Adducts; VIII. p-Arene Complexes; IX. Cyclooctatetraene Complexes; X. Carboranes; XI. Heterocyclopentadienyls; XII. Monocyclopentadienyl Complexes; XIII. Bis(cyclopentadienyl) Complexes; XIV. Bis(cyclopentadienyl) Ligand Variations; XV. Reactivity of (C5Me5)2Ln with Aluminum/Gallium Reagents; XVI. Isocarbonyls and Lanthanide Transition Metal Bonds; XVII. ?-C-H-Ln versus �-Si-Me-Ln Interactions; XVIII. Thermodynamics; XIX. Low Oxidation State Chemistry