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Field ionization mass spectrometry /
Field Ionization Mass Spectrometry focuses on developments in field ionization (FI) mass spectrometry and describes its applications in physical chemistry, with emphasis on mass spectrometric problems. Physico-chemical problems as well as problems of chemical analysis are considered based on issues...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford ; New York :
Pergamon Press,
1971.
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| Edición: | 1st ed. |
| Colección: | International series of monographs in analytical chemistry ;
42. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Field Ionization Mass Spectrometry; Copyright Page; Table of Contents; PREFACE; INTRODUCTION; I. PHYSICO-CHEMICAL PROBLEMS; II. PEOBLEMS OF CHEMICAL ANALYSIS; Chapter 1. THEORY OF FIELD IONIZATION (FI) AND FIELD EMISSION (FE); 1.1. FI Probability; 1.2. Particle Supply; 1.3. Minimum Distance for FI; 1.4. Field Electron Emission; Chapter 2. FIELD IONIZATION SOURCES; 2.1. General Design of FI Sources; 2.2. Tips as FI Emitters; 2.3. Thin Wires as FI Emitters; 2.4. Sharp Metal Edges as FI Emitters; 2.5. Comparison of Tips, Thin Wires and Sharp Metal Edges for FI
- 2.6. Means for Stabilizing Thin Wires During FI2.7. Actual Design of Some FI Sources; 2.8. Pulsed FI Sources; 2.9. FI Microscopes as Sources for Mass Spectrometers; 2.10. Resolving Power of FI Mass Spectrometers; Chapter 3. APPLICATION OF THE FI MASS SPECTROMETER TO PHYSICO-CHEMICAL PROBLEMS; 3.1. Charge Distribution of Organic Ions in High Electric Fields; 3.2. Field Dissociation of Molecular Ions; 3.3. Bond Energies of Molecular Ions; 3.4. Kinetics of Unimolecular Decomposition of Ions in High Electric Fields; 3.5. Temperature Dependence of FI Mass Spectra
- 3.6. Processes in Adsorbed Layers on FI Emitters3.7. Field-Induced Resonance States at a Surface; 3.8. Isotopie Effects in FI Mass Spectra; 3.9. Negative Ion Emission from Field Emitting Metal Surfaces; Chapter 4. QUALITATIVE ANALYSES WITH THE FI MASS SPECTROMETER; 4.1. FI Mass Spectra of Homologous Series of Organic Substances; 4.2. Detection of Free Radicals by FI Mass Spectrometry; 4.3. Elucidation of Structure, Mechanism and Kinetics of Decomposition of Organic Ions by FI Mass Spectrometry; 4.4. Quantitative Analyses of Mixtures; 5. REFERENCES; INDEX