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Electronic charges of bonds in organic compounds
Electronic Charges of Bonds in Organic Compounds presents simple and diverse methods for calculating the electronic charges of bonds from the results of physical methods of investigation. This book is composed of 10 chapters that consider the concept of electronic charges of bonds, which opened up p...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés Ruso |
| Publicado: |
Oxford, New York,
Pergamon Press; [distributed in the Western Hemisphere by Macmillan, New York]
1964.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Electronic Charges of Bonds in Organic Compounds; Copyright Page; Table of Contents ; PREFACE; CHAPTER I. HISTORICAL OUTLINE AND INTRODUCTION; 1. History of the classical and electronic theory of the structure of organic compounds; 2. Conception of electronic charges of bonds; 3. Introduction to the subsequent chapters; References; CHAPTER II. ELECTRONEGATIVITIES (ELECTRONOPHILIC NATURE) OF ATOMS; 1. Relationship between electronegativities of atoms and electronic bond charges; 2. Mechanism of the mutual effect of atoms; References; CHAPTER III. DIPOLE MOMENTS
- 4. Relationship between tf-electron charges and bond lengthsReferences; CHAPTER VI. HEATS OF FORMATION; 1. Two relationships between the ""heats of elementization"" of hydrocarbons and electronic bond charges; 2. Saturated hydrocarbons; 3. Unsaturated hydrocarbons; 4. Chlorine and bromine derivatives of paraffins; 5. Organic compounds containing oxygen; References; CHAPTER VII. HEAT EFFECTS OF ORGANIC REACTIONS; 1. Hydrogenation and bromination of ethylene and its homologues; 2. Isomerization of mono-olefins; References; CHAPTER VIII. ORGANIC RADICALS AND IONS
- 1. Radicals and dissociation energies of bonds2. Energy stability of carbanions and carbonium ions; References; CHAPTER IX. CHEMICAL PROPERTIES OF tf-BONDS; 1. Substitution reactions at a saturated carbon atom; 2. Cleavage reactions; References; CHAPTER X. CHEMICAL PROPERTIES OF �o�-BONDS; 1. Addition reactions; 2. Substitution reactions in benzene derivatives; References; CONCLUSION; SUBJECT INDEX