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Advances in carbohydrate chemistry and biochemistry /
Since its inception in 1945, this serial has provided critical and integrating articles written by research specialists that integrate industrial, analytical, and technological aspects of biochemistry, organic chemistry, and instrumentation methodology in the study of carbohydrates. The articles pro...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford, UK :
Elsevier,
2009.
|
| Colección: | Advances in carbohydrate chemistry & biochemistry ;
62 |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 100 | 1 | |a Horton, Derek. | |
| 245 | 1 | 0 | |a Advances in carbohydrate chemistry and biochemistry / |c Derek Horton. |
| 260 | |a Oxford, UK : |b Elsevier, |c 2009. | ||
| 300 | |a 1 online resource (424 pages) : |b illustrations. | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 490 | 0 | |a Advances in carbohydrate chemistry & biochemistry ; |v 62 | |
| 520 | |a Since its inception in 1945, this serial has provided critical and integrating articles written by research specialists that integrate industrial, analytical, and technological aspects of biochemistry, organic chemistry, and instrumentation methodology in the study of carbohydrates. The articles provide a definitive interpretation of the current status and future trends in carbohydrate chemistry and biochemistry. | ||
| 588 | 0 | |a Print version record. | |
| 505 | 0 | |a Front Cover; Advances in Carbohydrate Chemistry and Biochemistry; Copyright Page; Contents; List of Contributors; Preface; Chapter 1: Gerald Aspinall; Keynote Publications; Chapter 2: Vittorio Crescenzi; Chapter 3: Developments in the Karplus Equation as They Relate to the Nmr Coupling Constants Of Carbohydrates; I. Introduction; II. The Impact of Improved NMR Instrumentation; III. The Impact of Molecular Modeling; IV. Vicinal Coupling Constants; 1. ProtonProton Couplings; 2. ProtonCarbon Couplings; 3. ProtonNitrogen Couplings; 4. Phosphorus Couplings; 5. CarbonCarbon Couplings. | |
| 505 | 8 | |a V. Other Types of Vicinal Couplings1. Fluorine Couplings; 2. CarbonTin Couplings; VI. Couplings Over Four Bonds; 1. ProtonProton Couplings; VII. Couplings Over Five Bonds; 1. ProtonProton Couplings; VIII. Online Calculators for Coupling Constants and Torsions; IX. Summary; References; Chapter 4: Computational Studies of the Role of Glycopyranosyl Oxacarbenium Ions in Glycobiology and Glycochemistry; I. Introduction; 1. Importance of Glycopyranosyl Oxacarbenium Ions; II. Galactopyranosyl Oxacarbenium Ion as an Illustrative Model; 1. Background. | |
| 505 | 8 | |a 2. Isolated CationsRing and C5C6 SideChain Conformations3. Facially Selective MethanolOxacarbenium Ion Complexes; 4. The Orientations and Conformations of Side Chains at C2, C3, C4, and C5; 5. The Role of C2O2 Rotations, Including NeighboringGroup Participation; 6. The Role of Proton Transfer in the Transition State for Glycosylation Reactions; 7. Differences in Ionization Between and Donors; III. Conclusions and Future Directions; 1. Summary of Glycosylation Reaction Mechanisms; 2. Further Calculations Based on Existing Methodology; 3. Future Calculations Requiring Methodology Development. | |
| 505 | 8 | |a 4. Experimental Studies of GlycosylationAcknowledgments; References; Chapter 5: Oligosaccharide Synthesis: From Conventional Methods to Modern Expeditious Strategies; I. Introduction; II. Chemical Glycosylation and Conventional Oligosaccharide Synthesis; 1. Principles of Chemical Glycosylation; 2. Traditional Linear Oligosaccharide Synthesis; 3. Convergent Block Synthesis; III. Selective (LeavingGroup Based) Strategies; 1. Selective Activation; 2. TwoStep Activation and the In situ Preactivation; 3. ActiveLatent Strategy; 4. Orthogonal and Semiorthogonal Strategies. | |
| 505 | 8 | |a 5. Deactivation by Steric Hindrance6. Temporary Deactivation Concept; IV. Chemoselective (ProtectingGroup Based) Strategies; 1. Arming and Disarming with Neighboring Substituents; 2. ReactivityBased Programmable Strategy; 3. Disarming by the Remote Substituents; 4. Disarming by Torsional Effects; 5. SuperArmed Glycosyl Donors; V. RegioselectivityBased Strategies; 1. Hydroxyl Reactivity; 2. Triphenylmethyl Reactivity; 3. Bidirectional Approaches; VI. Novel Technologies for the Rapid and HighThroughput Oligosaccharide Synthesis; 1. OnePot Strategies. | |
| 650 | 0 | |a Chemistry, Organic. | |
| 650 | 2 | |a Chemistry, Organic |0 (DNLM)D002625 | |
| 650 | 6 | |a Chimie organique. |0 (CaQQLa)201-0004956 | |
| 650 | 7 | |a organic chemistry. |2 aat |0 (CStmoGRI)aat300054541 | |
| 650 | 7 | |a Chemistry, Organic |2 fast |0 (OCoLC)fst00853501 | |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780123747433 |z Texto completo |