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Equilibrium statistical mechanics
The International Encyclopedia of Physical Chemistry and Chemical Physics, Volume 1: Equilibrium Statistical Mechanics covers the fundamental principles and the development of theoretical aspects of equilibrium statistical mechanics. Statistical mechanical is the study of the connection between the...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford, New York,
Pergamon Press
[1968]
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| Edición: | [1st ed.]. |
| Colección: | International encyclopedia of physical chemistry and chemical physics (Oxford) ;
Topic 8: Statistical mechanics, v. 1. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- 2.2. Bose-Einstein, Fermi-Dirac and Boltzmann systems2.3. The classical limit; 2.4. Heat capacity and equipartition; 2.5. Symmetry number; 2.6. Isotopes; 2.7. Nuclear spin; 2.8. Coordinate transformations; CHAPTER 3. PERFECT GASES AND THE INTERNAL PARTITION FUNCTION; 3.1. Monatomic molecules; 3.2. Diatomic molecules; 3.3. The oscillator partition function; 3.4. The linear rotator function; 3.5. Molecular hydrogen; 3.6. Polyatomic molecules; 3.7. Polyatomic rotator function; 3.8. Polyatomic normal coordinates; 3.9. Polyatomic molecule symmetries; 3.10. Perfect gas thermodynamic functions
- CHAPTER 4. IMPERFECT GASES4.1. Introduction; 4.2. Simple cluster functions; 4.3. The virial expansion; 4.4. Proof of the virial development; 4.5. Interpretation of P/kT = bnzn; 4.6. Evaluation of the virial coefficients; 4.7. Condensation; 4.8. Plasma and the Debye limit; CHAPTER 5. SOLIDS; 5.1. Overall survey and electronic excitation; 5.2. Crystal lattice Hamiltonian; 5.3. Lattice vibration spectra; 5.4. The Debye lattice theory; 5.5. Debye thermodynamic functions; 5.6. Thermal expansion; 5.7. Crystal imperfections and order-disorder; CHAPTER 6. DENSE FLUIDS
- 6.1. Notation and the potential energy6.2. Distribution functions; 6.3. Equations for the distribution functions; 6.4. The potentials of average force; 6.5. The Kirkwood superposition assumption; 6.6. The virial of Clausius; 6.7. Calculation of Fn(z, T, {n}) from Fn(y, T, {n}); 6.8. The osmotic pressure; 6.9. The cluster development for osmotic pressure; 6.10. Moments and thermodynamic quantities; 6.11. Open and closed system moments; 6.12. Integral equations; 6.13. Monte Carlo; CHAPTER 7. QUANTUM STATISTICS; 7.1. Introduction; 7.2. Bose-Einstein perfect gases; 7.3. Black body radiation