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Chemical kinetics of gas reactions /
Chemical Kinetics of Gas Reactions explores the advances in gas kinetics and thermal, photochemical, electrical discharge, and radiation chemical reactions. This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés Ruso |
| Publicado: |
Oxford ; New York : [distributed by] Addison-Wesley Pub. Co., Reading, Mass.,
Pergamon Press ;
[1964]
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| Colección: | ADIWES international series in the physical sciences.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Chemical Kinetics of Gas Reactions; Copyright Page; Table of Contents; Foreword; CHAPTER 1. GENERAL KINETIC RULES FOR CHEMICAL REACTIONS; 1. Rate of reaction. Kinetic types of simple reactions; 2. Chemical equilibrium; 3. Complex reactions; CHAPTER 2. CHEMICAL MECHANISM OF REACTIONS; 4. Experimental methods for studying chemical reaction mechanisms ; 5. Intermediate substances; 6. Reactions of free atoms; 7. Free radical reactions; CHAPTER 3. THEORY OF ELEMENTARY CHEMICAL PROCESSES; 8. Elements of the statistical theory of elementary chemical processes
- 9. Gas-kinetic collision theory10. Potential energy of a system of atoms; 11. Qualitative consideration of energy changes in three-atom reactions; 12. Transition-state (activated-complex) method; 13. Quantum-mechanical treatment of the rate of elementary processes; CHAPTER 4. BIMOLECULAR REACTIONS; 14. Addition reactions A +B = AB; 15. Metathetical or transfer reactions A + BC = AB + C, and exchange (double transfer) reactions AB + CD = AC + BD; 16. Bimolecular dissociation reactions; 17. Dependence of the rate of transfer reactions on the structure of the reacting molecules
- CHAPTER 5. UNIMOLECULAR AND TERMOLECULAR REACTIONS18. Theory of unimolecular reactions; 19. Experimental data; 20. Termolecular reactions; CHAPTER 6. ENERGY CONVERSION DURING MOLECULAR COLLISIONS; 21. Transformation of translational and rotational energy; 22. Transformation of vibrational energy; CHAPTER 7. PHOTOCHEMICAL REACTIONS; 23. Photochemical activation of molecules; 24. Secondary processes during photochemical reactions; 25. Photochemical sensitization; 26. Quantum yield of photochemical reactions; 27. Temperature coefficient and mechanism of photochemical reactions
- CHAPTER 8. CHEMICAL REACTIONS IN ELECTRICAL DISCHARGE28. Activation in electrical discharge; 29. Activation by bombardment with fast ions and atoms; 30. Types of electrical discharge; 31. Chemical reactions in electrical discharge and yields of these reactions; 32. Chemical reactions taking place under the action of penetrating radiations (radiation-induced chemical reactions); CHAPTER 9. CHAIN REACTIONS; 33. Simple chain reactions; 34. Formal kinetics of chain reactions; 35. Chain initiation; 36. Chain breaking; 37. Branching chains; 38. Macroscopic stages in chain reactions
- 39. The combustion of hydrogen as a model reactionCHAPTER 10. COMBUSTION PROCESSES; 40. Spontaneous combustion; 41. Flames burning without preliminary mixing of the gases; 42. Flames burning in previously prepared mixtures; 43. Flame propagation; 44. Detonation; References; Name index; Subject index