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Phase equilibria : basic principles, applications, experimental techniques /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Reisman, A. (Arnold) (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York ; London : Academic Press, 1970.
Colección:Physical chemistry ; v. 19.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Thermodynamics and the phase rule
  • Definition of terms and concepts
  • The thermodynamic basis of the phase rule
  • Systems of one component-temperature effects
  • Systems of one component-pressure effects and the continuous nature of metastability
  • Complex metastability in one-component systems
  • Other aspects of one-component behavior
  • Enthalpy and entropy diagrams of state for unary systems
  • Multicomponent systems, homogeneous systems, and the equilibrium constant
  • Multicomponent systems, the equilibrium constant, and heterogeneous systems
  • The thermodynamic parameters-fugacity and activity two-component systems-systems in which one phase is pure and in which species and component mole terms are equivalentsimple eutectic interactions
  • Graphical representations of simple eutectic interactions
  • Eutectic systems continued-the parameter H-Fusion/ T melting and its influence on the contour of eutectic liquidus curves
  • The effects of homogeneous equilibria on liquidus contours
  • Common species effects in simple eutectic systems
  • The effects of association on liquidus contours
  • Effects of end member species interactions on liquidus contours
  • Effects of complete dissociation on liquidus contours
  • Graphical description of the results
  • Single compound formation in binary systems and coordinate transformations
  • Multiple compound formation in binary systems and coordinate transformations in multiple
  • p-T-Mx representations and phase changes
  • Intermediate compound instabilityincongruently melting compounds
  • Liquid immiscibility in eutectic systems
  • Systems exhibiting solid solubilityascending solid solutions
  • Graphical representation of idealized systems and some comment on real systems
  • Complete liquid phase dissociation and minimum type solid solutions
  • Hypothetical examples using the equations
  • Vapor phase binary diagrams
  • Incongruently vaporizing systems
  • Limited solid solubility
  • Three-component systems
  • Vapor equilibria chemical vapor transport reactions
  • Experimental techniques.