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An introduction to chemical metallurgy /
An Introduction to Chemical Metallurgy, Second Edition introduces the reader to chemical metallurgy, including its fundamental principles and some of their applications. References in the text to a date and the author of some law or principle of physical chemistry are given for the sake of historica...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford [England] ; New York :
Pergamon Press,
1978.
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| Edición: | 2d ed., in SI/metric units. |
| Colección: | Pergamon international library of science, technology, engineering, and social studies.
International series on materials science and technology ; v. 26. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; An Introduction to Chemical Metallurgy; Copyright Page; Table of Contents; Preface; Symbols and Abbreviations; CHAPTER 1. Introduction to Thermodynamics; 1.1. Introduction; 1.2. Energy; 1.3. The First Law of Thermodynamics; 1.4. The Expansion of a Gas: Thermodynamic Variables; 1.5. Thermodynamically Reversible Changes; 1.6. Heat Content or Enthalpy
- 1.7. Gas Expansion: Maximum Work; 1.8. Heat Capacity: The Temperature-dependence of Enthalpy Changes; 1.9. Thermochemistry and its Applications in Metallurgy; 1.10. Experimental Techniques in Calorimetry; References.
- CHAPTER 2. Entropy, Free Energy and Chemical Equilibrium2.1. Introduction; 2.2. The Statistical Nature of the Second Law of Thermodynamics; 2.3. A Different Approach to the Entropy Function:Cyclic Processes; 2.4. Some Thermodynamic Relationships Involving Entropy; 2.5. The Experimental Determination of Entropies; 2.6. The Driving Force behind a Chemical Reaction; 2.7. Free Energy; 2.8. Some Thermodynamic Relationships Involving Gibbs Free Energy; 2.9. Chemical Equilibrium: The Equilibrium Constant; 2.10. Controlled Atmospheres; 2.11. The Equilibrium Constant and the Stability of Compounds.
- 2.12. The Free Energy Change of a Reaction in Terms of the Concentrations of the Reactants and Products of the Reaction: The van't Hoff Isotherm2.13. The Relationship between the Equilibrium Constant and the Temperature of a Reaction: The van't Hoff Isochore and the Clausius-Clapeyron Equation; 2.14. Experimental Determination of Free Energy Changes; References; CHAPTER 3. Solutions; 3.1. Introduction; 3.2. Ideal Solutions: Raoult's Law; 3.3. Deviations from Raoult's Law; 3.4. Activities; 3.5. Henry's Law and Dilute Solutions: Changing the Standard State.
- 3.6. Experimental Determination of Activities3.7. The Effect of Additional Solutes on the Activity of the Original Solute of a Binary Solution:Interaction Coefficients; 3.8. Free Energy of Mixing; 3.9. Regular Solutions; 3.10. Partial Molar Quantities; 3.11. The Gibbs-Duhem Equation; 3.12. Excess Integral and Partial Molar Quantities; 3.13. Application of Free Energy-Composition Curves to the Study of Alloy Systems; References; CHAPTER 4. Reaction Kinetics; 4.1. Introduction; 4.2. Effect of Concentration of Reacting Substances.
- 4.3. Quantitative Relationships between Rate of Reaction and Concentration of Reactants4.4. Determination of the Order and Velocity Constant of a Reaction; 4.5. Reversible Reactions; 4.6. The Effect of Temperature on Rates of Reaction; 4.7. Theories of Reaction Kinetics: The Collision Theory; 4.8. The Activated Complex; 4.9. The Theory of Absolute Reaction Rates; 4.10. Unimolecular Reactions; 4.11. Catalysis; 4.12. Diffusion; 4.13. Diffusion in the Solid State(21); 4.14. Reaction Kinetics in Metallurgical Systems; References; CHAPTER 5. Electrochemistry; 5.1. Introduction; 5.2. Electrolytes.