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CH-acids : a guide to all existing problems of CH-acidity with new experimental methods and data, including indirect electrochemical, kinetic and thermodynamic studies /
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés Ruso |
| Publicado: |
Oxford [England] ; New York :
Pergamon Press,
1978.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Ch-Acids; Copyright Page; Table of Contents ; Preface; Chapter 1. Equilibrium Acidity of CH-Acids; I. Introduction; II. CH-Acidities in Water. A comparison with OH-Acids; III. Methods of Measuring Ionisation Equilibria of CH-Acids; Chapter 2. Structure Effects on Equilibrium CH-Acidity; I. Acidity in the Gas Phase; II. Acidity in Solution; Chapter 3. Kinetic CH-Acidity; I. Hydrogen Isotope Exchange. Protophilic Mechanism; II. Hydrogen Isotope Exchange Rates in CH-Acids of Various Types; III. Kinetic Isotope Effect and Exchange Mechanism.
- Chapter 4. Stereochemistry of Proton TransferI. Cyclopropane CH-Acids; II. Vinyl CH-Acids; III. CH-Acids with Substituents Containing Sulphur; IV. CH-Acids Forming Ambidental Anions; V. Fluorene CH-Acids; VI. Benzyl CH-Acids; VII. Proton Transfer Accompanied by Re-arrangements in Unsaturated Systems; Chapter 5. Relationship Between Equilibrium and Kinetic Acidity; I. Three-Step Proton Transfer Mechanism; II. Theoretical Interpretation of the Br�onsted Equation; III. ''Normal"" Bronsted Plots; IV. Correlations of Proton Transfer Rate with Acidity Function H-
- v. Bronsted Plots with Anomalous SlopesVI. H2O/OH- System; VII. Conclusion; References; Index; Additional References for 1975 to 1978.