Cargando…
Problems in metallurgical thermodynamics and kinetics /
Problems in Metallurgical Thermodynamics and Kinetics provides an illustration of the calculations encountered in the study of metallurgical thermodynamics and kinetics, focusing on theoretical concepts and practical applications. The chapters of this book provide comprehensive account of the theori...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Oxford ; New York :
Pergamon Press,
1977.
|
| Edición: | 1st ed. |
| Colección: | International series on materials science and technology ;
v. 25. Pergamon international library of science, technology, engineering, and social studies. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Problems in Metallurgical Thermodynamics and Kinetics; Copyright Page; Table of Contents; PREFACE; LIST OF SYMBOLS AND ABBREVIATIONS; CHAPTER 1. THE FIRST LAW OF THERMODYNAMICS; 1.1 Heat Content or Enthalpy; 1.2 Heat Capacity; 1.3 Thermochemistry and its Application in Metallurgy; 1.4 Hess's Law; 1.5 Variation of Enthalpy Change with Temperature; 1.6 Maximum Reaction Temperature : Flame Temperature; Exercises; CHAPTER 2. THE SECOND LAW OF THERMODYNAMICS : ENTROPY AND FREE ENERGY; 2.1 Entropy; 2.2 Entropy Change for a Reversible Process.
- 2.3 Entropy Change for an Irreversible Process2.4 Entropy Change for a Chemical Reaction; 2.5 Variation of Entropy Change with Temperature; 2.6 Criterion of Spontaneity based on Entropy; 2.7 Free Energy; 2.8 Criterion of Spontaneity based on Free Energy; 2.9 Calculation of Free Energy Change; 2.10 Calculation of AG at High Temperatures; 2.11 Gibbs Free Energy and Thermodynamic Functions; 2.12 Gibbs-Relmholtz Equation; Exercises; CHAPTER 3. THE THIRD LAW OF THERMODYNAMICS; 3.1 Statement of the Law; 3.2 Application; Exercises; CHAPTER 4. THE CLAUSIUS-CLAPEYRON EQUATION; 4.1 Introduction.
- 4.2 Application of Clausius-Clapeyron Equation to Phase Changes4.3 Trouton's Rule; Exercises; CHAPTER 5. FUGACITY, ACTIVITY AND EQUILIBRIUM CONSTANT; 5.1 Fugacity; 5.2 Activity; 5.3 Equilibrium Constant; 5.4 Vanft Hoff Equation; Exercises; CHAPTER 6. SOLUTIONS : I; 6.1 Introduction; 6.2 Partial Molar Quantities; 6.3 Gibbs-Duhem Equation; 6.4 Determination of Partial Molar Quantities from Molar Quantities; 6.5 Raoultls Law : Ideal Solutions; 6.6 Non-Ideal Solutions : Concept of Activity Coefficient; 6.7 Henry rs Law : Dilute Solutions; 6.8 Alternative Standard States; Exercises.
- CHAPTER 7. SOLUTIONS: II7.1 Sievert's Law; 7.2 Mixing Functions; 7.3 Excess Functions; 7.4 Regular Solutions; 7.5 Application of the Gibbs-Duhem Equation; 7.6 Multicomponent Solutions; Exercises; CHAPTER 8. THE THERMODYNAMICS OF ELECTROCHEMICAL CELLS; 8.1 Introduction; 8.2 Determination of Thermodynamic Quantities; 8.3 Electrochemical Cells based on Solid Electrolytes; Exercises; CHAPTER 9. KINETICS; 9.1 Introduction; 9.2 Effect of Concentration on the Reaction Rate; 9.3 Effect of Temperature on the Reaction Rate; 9.4 Determination of the Order of Reaction; 9.5 Theories of Reaction Kinetics.
- 9.6 Rate of Heterogeneous ReactionsExercises; APPENDIX 1: SI UNITS; APPENDIX 2: CONSTANTS AND CONVERSION FACTORS; APPENDIX 3: MATHEMATICAL OPERATIONS; BIBLIOGRAPHY; ANSWERS TO THE EXERCISES; INDEX; OTHER TITLES IN THE SERIES.