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The properties of water and their role in colloidal and biological systems /

This book treats the different current as well as unusual and hitherto often unstudied physico-chemical and surface-thermodynamic properties of water that govern all polar interactions occurring in it. These properties include the hyper-hydrophobicity of the water-air interface, the cluster formatio...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Van Oss, Carel J.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; London : Elsevier/Academic Press, 2008.
Colección:Interface science and technology ; v. 16.
Temas:
Acceso en línea:Texto completo
Texto completo

MARC

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100 1 |a Van Oss, Carel J. 
245 1 4 |a The properties of water and their role in colloidal and biological systems /  |c Carel Jan van Oss. 
260 |a Amsterdam ;  |a London :  |b Elsevier/Academic Press,  |c 2008. 
300 |a 1 online resource (xiv, 224 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a Interface science and technology ;  |v v. 16 
520 |a This book treats the different current as well as unusual and hitherto often unstudied physico-chemical and surface-thermodynamic properties of water that govern all polar interactions occurring in it. These properties include the hyper-hydrophobicity of the water-air interface, the cluster formation of water molecules in the liquid state and the concomitant variability of the ratio of the electron-accepticity to electron-donicity of liquid water as a function of temperature, T. The increase of that ratio with T is the cause of the increase in hydration repulsion (hydration pressure) between polar surfaces upon heating, when they are immersed in water. The book also treats the surface properties of apolar and polar molecules, polymers, particles and cells, as well as their mutual interaction energies, when immersed in water, under the influence of the three prevailing non-covalent forces, i.e., Lewis acid-base (AB), Lifshitz-van der Waals (LW) and electrical double layer (EL) interactions. The polar AB interactions, be they attractive or repulsive, typically represent up to 90% of the total interaction energies occurring in water. Thus the addition of AB energies to the LW + EL energies of the classical DLVO theory of energy vs. distance analysis makes this powerful tool (the Extended DLVO theory) applicable to the quantitative study of the stability of particle suspensions in water. The influence of AB forces on the interfacial tension between water and other condensed-phase materials is stressed and serves, inter alia, to explain, measure and calculate the driving force of the hydrophobic attraction between such materials (the ₃hydrophobic effect₄), when immersed in water. These phenomena, which are typical for liquid water, influence all polar interactions that take place in it. All of these are treated from the viewpoint of the properties of liquid water itself, including the properties of advancing freezing fronts and the surface properties of ice at 0o C. - Explains and allows the quantitative measurement of hydrophobic attraction and hydrophilic repulsion in water. Measures the degree of cluster formation of water molecules. Discusses the influence of temperature on the cluster size of water molecules. Treats the multitudinous effects of the hyper-hydrophobicity of the water-air interface. 
505 0 |a SECTION A. NON-COVALENT ENERGIES OF INTERACTION -- EQUATIONS AND COMBINING RULES -- SECTION B: SURFACE THERMODYNAMIC PROPERTIES OF WATER WITH RESPECT TO CONDENSED-PHASE MATERIALS IMMERSED IN IT -- SECTION C: PHYSICAL AND PHYSICOCHEMICAL PROPERTIES OF WATER. 
504 |a Includes bibliographical references and index. 
588 0 |a Print version record. 
650 0 |a Water  |x Analysis. 
650 0 |a Water  |x Properties. 
650 0 |a Surface chemistry. 
650 0 |a Surfaces (Physics) 
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650 6 |a Eau  |0 (CaQQLa)201-0008793  |x Propri�et�es.  |0 (CaQQLa)000259372 
650 6 |a Chimie des surfaces.  |0 (CaQQLa)201-0000376 
650 6 |a Surfaces (Physique)  |0 (CaQQLa)201-0050017 
650 7 |a SCIENCE  |x Chemistry  |x Inorganic.  |2 bisacsh 
650 7 |a Surface chemistry.  |2 fast  |0 (OCoLC)fst01139210 
650 7 |a Surfaces (Physics)  |2 fast  |0 (OCoLC)fst01139265 
650 7 |a Water  |x Analysis.  |2 fast  |0 (OCoLC)fst01171149 
776 0 8 |i Print version:  |a Van Oss, Carel J.  |t Properties of water and their role in colloidal and biological systems.  |d Amsterdam ; London : Elsevier/Academic Press, 2008  |z 9780123743039  |z 0123743036  |w (OCoLC)229031857 
830 0 |a Interface science and technology ;  |v v. 16. 
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