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Catalytic olefin polymerization : proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts, Tokyo, October 23-25, 1989 /

Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for poly...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor Corporativo: International Symposium on Recent Developments in Olefin Polymerization Catalysts Tokyo, Japan
Otros Autores: Keii, Tominaga, 1920-2007, Soga, Kazuo, 1939-
Formato: Electrónico Congresos, conferencias eBook
Idioma:Inglés
Publicado: Tokyo : Amsterdam ; New York : Kodansha ; Elsevier, 1990.
Colección:Studies in surface science and catalysis ; 56.
Temas:
Acceso en línea:Texto completo
Texto completo

MARC

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245 1 0 |a Catalytic olefin polymerization :  |b proceedings of the International Symposium on Recent Developments in Olefin Polymerization Catalysts, Tokyo, October 23-25, 1989 /  |c edited by Tominaga Keii, Kazuo Soga. 
260 |a Tokyo :  |b Kodansha ;  |a Amsterdam ;  |a New York :  |b Elsevier,  |c 1990. 
300 |a 1 online resource (xvi, 574 pages) :  |b illustrations 
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490 1 |a Studies in surface science and catalysis ;  |v vol. 56 
520 |a Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems. The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems. 
504 |a Includes bibliographical references. 
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505 0 |a Front Cover -- Catalytic Olefin Polymerization -- Copyright Page -- Contents -- List of Contributors -- Preface -- Chapter 1. A Theory of Time-Invariant Molecular Weight Distributions in Heterogeneous Ziegler-Natta Polymerizations -- Chapter 2. Studies on the Polymerization of Propylene Using Highly Active Magnesium Chloride Supported Ziegler-Natta Catalysts : Effects of Alkyl Concentration on the Polymerization Rate and on the Active Centre Concentration -- Chapter 3. Gas Phase Polymerization of Propene with MgCl2 Supported Catalyst. 
505 8 |a Chapter 4. Ethylene Polymerization in Gas-Phase and Slurry Reactors -- Chapter 5. Differences in Kinetic Parameters of Various Kinds of MgCl2-Sup-ported High Yield Catalysts -- Chapter 6. Kinetic Profile of Polymerization with Cr-Oxide/SiO2 Catalyst -- Chapter 7. Effects of the Structure of External Alkoxy Silane Donor in High Activity Ziegler-Natta Catalyst on the Microstructure of Polypropylene -- Chapter 8. Active Center Selection and Propene Polymerization Control with the New Supported Ziegler-Natta Catalysts. 
505 8 |a Chapter 9. Control of the Catalyst and Polymer Properties of Linear Polyethylenes -- Chapter 10. Easy Conversion of Aspecific into Isospecific Sites -- Chapter 11. A 13C CP-MAS NMR and Elemental Analysis Study of Adsorption of Silyl Ethers on the MgCl2-Supported Ziegler-Natta Catalysts -- Chapter 12. Infrared Characterization of Supported Propylene Polymerization Catalysts-A Link to Catalyst Performance -- Chapter 13. Microtacticity Distribution of Polypropylenes Prepared with MgCl2 Supported Ti Catalyst Systems. 
505 8 |a Chapter 14. Development of SiO2-Supported Type Catalyst for Propylene Molymerization -- Chapter 15. Effect of Silane Compounds on Catalyst Isospecificity -- A Plausible Model Based on MO Calculation -- Chapter 16. 13C NMR Investigation on Lewis Base Activation Effect in High Yield Supported Ziegler-Natta Catalysts -- Chapter 17. A New Electron Donor for the Stereospecific Polymerization of Propene -- Chapter 18. Formation of Cationic Species and Additive Effect of Ethyl Benzoate on Polymerization of Isobutene and Styrene with TiCl3 -Alkylaluminum Catalyst. 
505 8 |a Chapter 19. Co- and Terpolymerization of Ethene and Higher �-Olefins with MgH2 Supported Ziegler Catalysts : New Mechanistic Insight via the True Reactivity Ratios -- Chapter 20. Co- and Terpolymerization of Ethylene, Propylene and Butadiene with Supported Titanium Catalyst -- Chapter 21. Kinetics of Ethylene -Propylene Copolymerization over MgCl2 -Supported Catalysts -- Chapter 22. A Study on the Active Sites of a Primary Type of MgCl2-Supported Catalyst by Ethylene-Propylene Copolymerization. 
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