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Advances in catalysis. Volume 38 /

Since 1948, this Series has filled the gap between the papers that report and the textbooks that teach in the diverse areas of catalysis research. The editors of and contributors to Advances in Catalysis are dedicated to recording progress in this area. Each volume of Advances in Catalysis contains...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Eley, D. D., Pines, Herman, 1902-1996, Weisz, Paul Burg, 1919-
Formato: Electrónico eBook
Idioma:Inglés
Publicado: San Diego : Academic Press, 1992.
Colección:Advances in Catalysis.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Front Cover; Advances in Catalysis, Volume 38; Copyright Page; Contents; Contributors; Preface; Chapter 1. Behavior and Characterization of Kinetically Involved Chemisorbed Intermediates in Electrocatalysis of Gas Evolution Reactions; I. Scope of Review; II. Relation of Electrocatalysis to Catalysis; III. Conditions for Electron Charge Transfer with Adsorption of an Intermediate; IV. Characterization of Kinetically Involved Adsorbed Intermediates in Regular Heterogeneous Catalysis; V. Chemical Identity of Adsorbed Intermediates in Electrocatalysis.
  • VI. Involvement of Chemisorbed Intermediates in Electrode Reactions, and Methods of AnalysisVII. Tafel Slope Factor in Electrocatalysis and Its Relation to Chemisorption of Intermediates; VIII. Relations between Tafel and Potential-Decay Slopes; IX. Tafel Slopes and Potential Dependence of Coverage by Intermediates; X. Reaction Order in Relation to Reaction Mechanisms and Adsorption of Reactants and Intermediates; XI. Real-Area Factor in Electrocatalysis; XII. Electrocatalysis in Cathodic Hydrogen Evolution and Nature of Electrode Metal.
  • XIII. In Situ Activation of Cathodes for Hydrogen Evolution by ElectrodepositionXIV. Electrocatalysis at Glassy Metals; XV. Determination of Coverage by Adsorbed H in Hydrogen Evolution Reaction at Transition Metals; XVI. Metal Film Electrocatalytic Effects in Photoelectrolysis Processes; XVII. Electrocatalysis and Kinetic Behavior of Oxygen Evolution Reaction; XVIII. Electrode Kinetic Behavior of Chlorine Evolution Reaction, and Role and Identity of Adsorbed Intermediates; XIX. Electronic and Structural Features of Oxide Electrocatalysts for Chlorine and Oxygen Evolution; References.
  • Chapter 2. Applications of Adsorption Microcalorimetry to the Study of Heterogeneous CatalysisI. Introduction; II. Theoretical Background; III. Calorimetric Principles; IV. Study of the Acid-Base Properties of Oxide Surfaces; V. Acid-Base Properties of Zeolites; VI. Acid-Base Properties of Amorphous Metal Oxides; VII. Acid-Base Discussion; VIII. Properties of Metals and Supported Metals; IX. Catalytic Applications; X. Conclusions; References; Chapter 3. Organic Syntheses Using Aluminosilicates; I. Introduction; II. Organic Reactions on Zeolites; III. Reactions on Clay; IV. Epilog; References.
  • Chapter 4. Metal Cluster Compounds as Molecular Precursors for Tailored Metal CatalystsI. Introduction; II. Characterization of Clusters on Surfaces; III. Structure and Reactivity of Clusters on Surfaces; IV. Cluster-Derived Homometal Catalysts; V. Cluster-Derived Bimetallic Catalysts; VI. Clusters in Zeolites; VII. Clusters on Other Supports; VIII. Summary and Prospects; References; Index.