Unimolecular kinetics /

Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long t...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Green, N. J. B.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; Boston : Elsevier, 2003.
Edición:1st ed.
Colección:Comprehensive chemical kinetics ; v. 39.
Temas:
Chemical kinetics.
Unimolecular reactions.
Cin�etique chimique.
R�eactions monomol�eculaires.
Acceso en línea:Texto completo
Texto completo
Tabla de Contenidos:
  • Cover
  • Contents
  • Preface
  • Chapter 1. Introduction
  • 1. Introduction
  • 2. Failures of the Lindemann Theory
  • 3. RKK Theory
  • 4. Slater Theory
  • 5. RKKM theory
  • 6. Statistical adiabatic channel model
  • 7. Improved models of energy transfer
  • References
  • Chapter 2. RRKM Theory and Its Implementation
  • 2.1. Background
  • 2.2. Derivation of RRKM theory
  • 2.3. Reactions with barriers
  • 2.4. Vibrational anharmonicities and non-rigidities
  • 2.5. Barrierless reactions
  • 2.6. Summary
  • Acknowledgements
  • References
  • Chapter 3. State-specific dynamics of unimolecular dissociation
  • 1. Introduction
  • 2. Resonance formulation of unimolecular decay
  • 3. Experimental approaches
  • 4. Computational methods
  • 5. Mode-specific dissociation
  • 6. Statistical state-specific dissociation
  • 7. Product state distributions
  • 8. Classical calculations
  • 9. Outlook
  • Acknowledgements
  • References
  • Index
  • Last Page.

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