Cargando…
Synthesis of acetylenes, allenes and cumulenes : methods and techniques /
There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The Best Synthetic Methods series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real advant...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; Boston :
Elsevier : Academic Press,
2004.
|
| Edición: | 1st ed. |
| Colección: | Best synthetic methods.
Studies in organic chemistry (Elsevier Scientific Publishing Company) ; 8. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Procedures and Equipment. Preparation, Purification and Storage of Some Solvents and Reagents. Generation of Metallated Acetylenes, Allenes and Cumulenes. Reactions of Metallated Acetylenes and Allenes with Alkylating Agents. Reactions with Aldehydes and Ketones. Carboxylation, Acylation and Related Reactions. Silylation, Stannylation and Phosphorylation. Sulfenylation and Related Reactions. Halogenation of Acetylenes. Acetylenes, Allenes and Cumulenes by Elimination Reactions. Cumulenes by Dehalogenation of Geminal Dihalogenocyclopropanes. Acetylenic and Allenic Derivatives by Substitution on sp- and sp<sup>2</sup>-Carbon. Aminoalkylation of Acetylenic Compounds. Cross-Coupling between 1-Alkynes and 1-Bromo-1-alkynes. Copper Halide-Catalysed Oxidative Coupling of Acetylenes. Transition Metals-Catalysed Couplings of Acetylenes with sp<sup>2</sup>-Halides. Base-Catalysed Isomerisations of Acetylenic Compounds. Allenic Compounds by 2,3- and 3,3-Sigmatropic Rearrangements. Miscellaneous Reactions of Acetylenic and Allenic Compounds. Transformation of Functional Groups in Acetylenic and Allenic Compounds.